Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN=NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

Shivaiah Vaddypally; Sandeep K. Kondaveeti; John H. Roudebush; Robert J. Cava; Michael J. Zdilla

doi:10.1039/c3cc42165a

Formation of the tetranuclear, tetrakis-terminal-imido Mn₄^IV(N^tBu)₈ cubane cluster by four-electron reductive elimination of ^tBuN=N^tBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

Shivaiah Vaddypally, Sandeep K. Kondaveeti, John H. Roudebush, Robert J. Cava, Michael J. Zdilla

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Mn₄^IV(μ₃-N^tBu)₄(N^tBu)₄ is obtained from a previously reported asymmetric Mn^IV/V–Li–(NR)(N) cluster by the removal of Li from the starting cluster by ion metathesis, which triggers reductive elimination of azo-tert-butane to give a tetranuclear heterocubane cluster.

Original language	English (US)
Pages (from-to)	1061-1063
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	9
DOIs	https://doi.org/10.1039/c3cc42165a
State	Published - Dec 24 2014

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Vaddypally, S., Kondaveeti, S. K., Roudebush, J. H., Cava, R. J., & Zdilla, M. J. (2014). Formation of the tetranuclear, tetrakis-terminal-imido Mn₄^IV(N^tBu)₈ cubane cluster by four-electron reductive elimination of ^tBuN=N^tBu. The role of the s-block ion in stabilization of high-oxidation state intermediates. Chemical Communications, 50(9), 1061-1063. https://doi.org/10.1039/c3cc42165a

@article{435ddc9d8a1c4c4ca4728035aa60caa0,

title = "Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN=NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates",

abstract = "Mn4IV(μ3-NtBu)4(NtBu)4 is obtained from a previously reported asymmetric MnIV/V–Li–(NR)(N) cluster by the removal of Li from the starting cluster by ion metathesis, which triggers reductive elimination of azo-tert-butane to give a tetranuclear heterocubane cluster.",

author = "Shivaiah Vaddypally and Kondaveeti, {Sandeep K.} and Roudebush, {John H.} and Cava, {Robert J.} and Zdilla, {Michael J.}",

year = "2014",

month = dec,

day = "24",

doi = "10.1039/c3cc42165a",

language = "English (US)",

volume = "50",

pages = "1061--1063",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "9",

}

Vaddypally, S, Kondaveeti, SK, Roudebush, JH, Cava, RJ & Zdilla, MJ 2014, 'Formation of the tetranuclear, tetrakis-terminal-imido Mn₄^IV(N^tBu)₈ cubane cluster by four-electron reductive elimination of ^tBuN=N^tBu. The role of the s-block ion in stabilization of high-oxidation state intermediates', Chemical Communications, vol. 50, no. 9, pp. 1061-1063. https://doi.org/10.1039/c3cc42165a

Formation of the tetranuclear, tetrakis-terminal-imido Mn₄^IV(N^tBu)₈ cubane cluster by four-electron reductive elimination of ^tBuN=N^tBu. The role of the s-block ion in stabilization of high-oxidation state intermediates. / Vaddypally, Shivaiah; Kondaveeti, Sandeep K.; Roudebush, John H. et al.
In: Chemical Communications, Vol. 50, No. 9, 24.12.2014, p. 1061-1063.

Research output: Contribution to journal › Article › peer-review

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T1 - Formation of the tetranuclear, tetrakis-terminal-imido Mn4IV(NtBu)8 cubane cluster by four-electron reductive elimination of tBuN=NtBu. The role of the s-block ion in stabilization of high-oxidation state intermediates

AU - Vaddypally, Shivaiah

AU - Kondaveeti, Sandeep K.

AU - Roudebush, John H.

AU - Cava, Robert J.

AU - Zdilla, Michael J.

PY - 2014/12/24

Y1 - 2014/12/24

N2 - Mn4IV(μ3-NtBu)4(NtBu)4 is obtained from a previously reported asymmetric MnIV/V–Li–(NR)(N) cluster by the removal of Li from the starting cluster by ion metathesis, which triggers reductive elimination of azo-tert-butane to give a tetranuclear heterocubane cluster.

AB - Mn4IV(μ3-NtBu)4(NtBu)4 is obtained from a previously reported asymmetric MnIV/V–Li–(NR)(N) cluster by the removal of Li from the starting cluster by ion metathesis, which triggers reductive elimination of azo-tert-butane to give a tetranuclear heterocubane cluster.

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U2 - 10.1039/c3cc42165a

DO - 10.1039/c3cc42165a

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JO - Chemical Communications

JF - Chemical Communications

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