Formation of dissipative structures in microscopic models of mixtures with species interconversion

Thomas J. Longo, Nikolay A. Shumovskyi, Betül Uralcan, Sergey V. Buldyrev, Mikhail A. Anisimov, Pablo G. Debenedetti

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The separation of substances into different phases is ubiquitous in nature and important scientifically and technologically. This phenomenon may become drastically different if the species involved, whether molecules or supramolecular assemblies, interconvert. In the presence of an external force large enough to overcome energetic differences between the interconvertible species (forced interconversion), the two alternative species will be present in equal amounts, and the striking phenomenon of steady-state, restricted phase separation into mesoscales is observed. Such microphase separation is one of the simplest examples of dissipative structures in condensed matter. In this work, we investigate the formation of such mesoscale steady-state structures through Monte Carlo and molecular dynamics simulations of three physically distinct microscopic models of binary mixtures that exhibit both equilibrium (natural) interconversion and a nonequilibrium source of forced interconversion. We show that this source can be introduced through an internal imbalance of intermolecular forces or an external flux of energy that promotes molecular interconversion, possible manifestations of which could include the internal nonequilibrium environment of living cells or a flux of photons. The main trends and observations from the simulations are well captured by a nonequilibrium thermodynamic theory of phase transitions affected by interconversion. We show how a nonequilibrium bicontinuous microemulsion or a spatially modulated state may be generated depending on the interplay between diffusion, natural interconversion, and forced interconversion.

Original languageEnglish (US)
Article numbere2215012120
JournalProceedings of the National Academy of Sciences of the United States of America
Volume120
Issue number1
DOIs
StatePublished - Jan 3 2023

All Science Journal Classification (ASJC) codes

  • General

Keywords

  • dissipative structures
  • molecular interconversion
  • phase separation

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