Formal synthesis of teleocidin a via indole-Cr(CO)3 complexes

M. F. Semmelhack; Hakjune Rhee

doi:10.1016/S0040-4039(00)60301-5

Formal synthesis of teleocidin a via indole-Cr(CO)₃ complexes

M. F. Semmelhack
, Hakjune Rhee

Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The addition of a cyano-stabilized anion to a 4-aminoindole-Cr(CO)₃ complex can be directed to selective C-7 substitution, and the resulting intermediate is part of a formal total synthesis of teleocidin A1/A2.

Original language	English (US)
Pages (from-to)	1399-1402
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)60301-5
State	Published - Feb 26 1993

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)60301-5

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@article{fd894d5d1f0b490983b9365471ecf991,

title = "Formal synthesis of teleocidin a via indole-Cr(CO)3 complexes",

abstract = "The addition of a cyano-stabilized anion to a 4-aminoindole-Cr(CO)3 complex can be directed to selective C-7 substitution, and the resulting intermediate is part of a formal total synthesis of teleocidin A1/A2.",

author = "Semmelhack, \{M. F.\} and Hakjune Rhee",

note = "Funding Information: 17. The preparationo f complex 11 was attemptedu nder various conditions. Most effective appeared to be the use of 2.0 mol-equlvo f (CHsCN)8(CO)sCr in dloxane at 60 OC. 18. We acknowledges upport from the Public Health Service (NIH GM31352).",

year = "1993",

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day = "26",

doi = "10.1016/S0040-4039(00)60301-5",

language = "English (US)",

volume = "34",

pages = "1399--1402",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "9",

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T1 - Formal synthesis of teleocidin a via indole-Cr(CO)3 complexes

AU - Semmelhack, M. F.

AU - Rhee, Hakjune

N1 - Funding Information: 17. The preparationo f complex 11 was attemptedu nder various conditions. Most effective appeared to be the use of 2.0 mol-equlvo f (CHsCN)8(CO)sCr in dloxane at 60 OC. 18. We acknowledges upport from the Public Health Service (NIH GM31352).

PY - 1993/2/26

Y1 - 1993/2/26

N2 - The addition of a cyano-stabilized anion to a 4-aminoindole-Cr(CO)3 complex can be directed to selective C-7 substitution, and the resulting intermediate is part of a formal total synthesis of teleocidin A1/A2.

AB - The addition of a cyano-stabilized anion to a 4-aminoindole-Cr(CO)3 complex can be directed to selective C-7 substitution, and the resulting intermediate is part of a formal total synthesis of teleocidin A1/A2.

UR - https://www.scopus.com/pages/publications/0027461856

UR - https://www.scopus.com/pages/publications/0027461856#tab=citedBy

U2 - 10.1016/S0040-4039(00)60301-5

DO - 10.1016/S0040-4039(00)60301-5

M3 - Article

AN - SCOPUS:0027461856

SN - 0040-4039

VL - 34

SP - 1399

EP - 1402

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 9

ER -

Formal synthesis of teleocidin a via indole-Cr(CO)₃ complexes

Abstract

All Science Journal Classification (ASJC) codes

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