Flow reactor studies of carbon monoxide/hydrogen/oxygen kinetics

R. A. Yetter; F. L. Dryer; H. Rabitz

doi:10.1080/00102209108951760

Flow reactor studies of carbon monoxide/hydrogen/oxygen kinetics

R. A. Yetter, F. L. Dryer, H. Rabitz

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

New data on the kinetics of CO/H_2O/O₂and H₂/O₂mixtures in the temperature range of 852–1138 K and at 1 atmosphere pressure are reported. The data were obtained from adiabatic, constant pressure flow reactor experiments for variations in the initial carbon, hydrogen, and oxygen contents of the mixture and also for variations in the initial temperature. In particular, the results define explosion limit temperatures for near stoichiometric mixtures of CO/H₂O/O₂and H₂/O₂systems at atmospheric pressure without the presence of surfaces and also demonstrate the complex relationship between water vapor concentration and the carbon monoxide oxidation rate.

Original language	English (US)
Pages (from-to)	129-140
Number of pages	12
Journal	Combustion science and technology
Volume	79
Issue number	1-3
DOIs	https://doi.org/10.1080/00102209108951760
State	Published - Sep 1 1991

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology
General Physics and Astronomy

Keywords

CO/H
flow reactor
kinetics

Access to Document

10.1080/00102209108951760

Cite this

@article{5ed4af685eec479588faa3db9cdaa29d,

title = "Flow reactor studies of carbon monoxide/hydrogen/oxygen kinetics",

abstract = "New data on the kinetics of CO/H2O/O2and H2/O2mixtures in the temperature range of 852–1138 K and at 1 atmosphere pressure are reported. The data were obtained from adiabatic, constant pressure flow reactor experiments for variations in the initial carbon, hydrogen, and oxygen contents of the mixture and also for variations in the initial temperature. In particular, the results define explosion limit temperatures for near stoichiometric mixtures of CO/H2O/O2and H2/O2systems at atmospheric pressure without the presence of surfaces and also demonstrate the complex relationship between water vapor concentration and the carbon monoxide oxidation rate.",

keywords = "CO/H, flow reactor, kinetics",

author = "Yetter, {R. A.} and Dryer, {F. L.} and H. Rabitz",

note = "Funding Information: The authors acknowledge support from the u.s. Department of Energy, Division of Chemical Sciences, Office of Basic Energy Sciences, under Grant No. DE-FG02-86ER 13503. The technical assistance of Messrs. J. Sivo and D. Peoples in conducting the experiments is greatly appreciated.",

year = "1991",

month = sep,

day = "1",

doi = "10.1080/00102209108951760",

language = "English (US)",

volume = "79",

pages = "129--140",

journal = "Combustion science and technology",

issn = "0010-2202",

publisher = "Taylor and Francis Ltd.",

number = "1-3",

}

TY - JOUR

T1 - Flow reactor studies of carbon monoxide/hydrogen/oxygen kinetics

AU - Yetter, R. A.

AU - Dryer, F. L.

AU - Rabitz, H.

N1 - Funding Information: The authors acknowledge support from the u.s. Department of Energy, Division of Chemical Sciences, Office of Basic Energy Sciences, under Grant No. DE-FG02-86ER 13503. The technical assistance of Messrs. J. Sivo and D. Peoples in conducting the experiments is greatly appreciated.

PY - 1991/9/1

Y1 - 1991/9/1

N2 - New data on the kinetics of CO/H2O/O2and H2/O2mixtures in the temperature range of 852–1138 K and at 1 atmosphere pressure are reported. The data were obtained from adiabatic, constant pressure flow reactor experiments for variations in the initial carbon, hydrogen, and oxygen contents of the mixture and also for variations in the initial temperature. In particular, the results define explosion limit temperatures for near stoichiometric mixtures of CO/H2O/O2and H2/O2systems at atmospheric pressure without the presence of surfaces and also demonstrate the complex relationship between water vapor concentration and the carbon monoxide oxidation rate.

AB - New data on the kinetics of CO/H2O/O2and H2/O2mixtures in the temperature range of 852–1138 K and at 1 atmosphere pressure are reported. The data were obtained from adiabatic, constant pressure flow reactor experiments for variations in the initial carbon, hydrogen, and oxygen contents of the mixture and also for variations in the initial temperature. In particular, the results define explosion limit temperatures for near stoichiometric mixtures of CO/H2O/O2and H2/O2systems at atmospheric pressure without the presence of surfaces and also demonstrate the complex relationship between water vapor concentration and the carbon monoxide oxidation rate.

KW - CO/H

KW - flow reactor

KW - kinetics

UR - http://www.scopus.com/inward/record.url?scp=84954733792&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84954733792&partnerID=8YFLogxK

U2 - 10.1080/00102209108951760

DO - 10.1080/00102209108951760

M3 - Article

AN - SCOPUS:84954733792

SN - 0010-2202

VL - 79

SP - 129

EP - 140

JO - Combustion science and technology

JF - Combustion science and technology

IS - 1-3

ER -

Flow reactor studies of carbon monoxide/hydrogen/oxygen kinetics

Abstract

All Science Journal Classification (ASJC) codes

Keywords

Access to Document

Other files and links

Fingerprint

Cite this