Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds

Mark J. Pouy; Erika M. Milczek; Travis M. Figg; Brooke M. Otten; Bruce M. Prince; T. Brent Gunnoe; Thomas R. Cundari; John Taylor Groves

doi:10.1021/ja3054139

Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds

Mark J. Pouy, Erika M. Milczek, Travis M. Figg, Brooke M. Otten, Bruce M. Prince, T. Brent Gunnoe, Thomas R. Cundari, John Taylor Groves

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Flavins and related molecules catalyze organic Baeyer-Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal-carbon bonds through a Baeyer-Villiger-like transition state.

Original language	English (US)
Pages (from-to)	12920-12923
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	31
DOIs	https://doi.org/10.1021/ja3054139
State	Published - Aug 8 2012

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja3054139

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title = "Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds",

abstract = "Flavins and related molecules catalyze organic Baeyer-Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal-carbon bonds through a Baeyer-Villiger-like transition state.",

author = "Pouy, \{Mark J.\} and Milczek, \{Erika M.\} and Figg, \{Travis M.\} and Otten, \{Brooke M.\} and Prince, \{Bruce M.\} and Gunnoe, \{T. Brent\} and Cundari, \{Thomas R.\} and Groves, \{John Taylor\}",

year = "2012",

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doi = "10.1021/ja3054139",

language = "English (US)",

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journal = "Journal of the American Chemical Society",

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T1 - Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds

AU - Pouy, Mark J.

AU - Milczek, Erika M.

AU - Figg, Travis M.

AU - Otten, Brooke M.

AU - Prince, Bruce M.

AU - Gunnoe, T. Brent

AU - Cundari, Thomas R.

AU - Groves, John Taylor

PY - 2012/8/8

Y1 - 2012/8/8

N2 - Flavins and related molecules catalyze organic Baeyer-Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal-carbon bonds through a Baeyer-Villiger-like transition state.

AB - Flavins and related molecules catalyze organic Baeyer-Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal-carbon bonds through a Baeyer-Villiger-like transition state.

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U2 - 10.1021/ja3054139

DO - 10.1021/ja3054139

M3 - Article

C2 - 22827584

AN - SCOPUS:84864644001

SN - 0002-7863

VL - 134

SP - 12920

EP - 12923

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 31

ER -

Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds

Abstract

All Science Journal Classification (ASJC) codes

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