Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds

Mark J. Pouy, Erika M. Milczek, Travis M. Figg, Brooke M. Otten, Bruce M. Prince, T. Brent Gunnoe, Thomas R. Cundari, John Taylor Groves

Research output: Contribution to journalArticlepeer-review

35 Scopus citations


Flavins and related molecules catalyze organic Baeyer-Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal-carbon bonds through a Baeyer-Villiger-like transition state.

Original languageEnglish (US)
Pages (from-to)12920-12923
Number of pages4
JournalJournal of the American Chemical Society
Issue number31
StatePublished - Aug 8 2012

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Biochemistry
  • Catalysis
  • Colloid and Surface Chemistry


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