EXAFS analysis of plasticized zinc‐neutralized sulfonated polystyrene ionomers

Y. S. Ding; R. A. Register; M. R. Nagarajan; H. K. Pan; S. L. Cooper

doi:10.1002/polb.1988.090260207

EXAFS analysis of plasticized zinc‐neutralized sulfonated polystyrene ionomers

Y. S. Ding, R. A. Register, M. R. Nagarajan, H. K. Pan, S. L. Cooper

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The interaction of several plasticizers with the zinc cation in zinc‐neutralized sulfonated polystyrene was examined with extended x‐ray absorption fine structure (EXAFS) spectroscopy. Glycerol and water were found to interact strongly with the zinc cation, plasticizing the ionic aggregates. At full solvation by glycerol, the zinc atom was found to be coordinated by three glycerol molecules. Dioctylphthalate, acetonitrile, and toluene, which are unable to coordinate to the zinc cation, were found to have a minimal effect on the cation's local structure.

Original language	English (US)
Pages (from-to)	289-300
Number of pages	12
Journal	Journal of Polymer Science Part B: Polymer Physics
Volume	26
Issue number	2
DOIs	https://doi.org/10.1002/polb.1988.090260207
State	Published - Feb 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Physical and Theoretical Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/polb.1988.090260207

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title = "EXAFS analysis of plasticized zinc‐neutralized sulfonated polystyrene ionomers",

abstract = "The interaction of several plasticizers with the zinc cation in zinc‐neutralized sulfonated polystyrene was examined with extended x‐ray absorption fine structure (EXAFS) spectroscopy. Glycerol and water were found to interact strongly with the zinc cation, plasticizing the ionic aggregates. At full solvation by glycerol, the zinc atom was found to be coordinated by three glycerol molecules. Dioctylphthalate, acetonitrile, and toluene, which are unable to coordinate to the zinc cation, were found to have a minimal effect on the cation's local structure.",

author = "Ding, {Y. S.} and Register, {R. A.} and Nagarajan, {M. R.} and Pan, {H. K.} and Cooper, {S. L.}",

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AU - Register, R. A.

AU - Nagarajan, M. R.

AU - Pan, H. K.

AU - Cooper, S. L.

PY - 1988/2

Y1 - 1988/2

N2 - The interaction of several plasticizers with the zinc cation in zinc‐neutralized sulfonated polystyrene was examined with extended x‐ray absorption fine structure (EXAFS) spectroscopy. Glycerol and water were found to interact strongly with the zinc cation, plasticizing the ionic aggregates. At full solvation by glycerol, the zinc atom was found to be coordinated by three glycerol molecules. Dioctylphthalate, acetonitrile, and toluene, which are unable to coordinate to the zinc cation, were found to have a minimal effect on the cation's local structure.

AB - The interaction of several plasticizers with the zinc cation in zinc‐neutralized sulfonated polystyrene was examined with extended x‐ray absorption fine structure (EXAFS) spectroscopy. Glycerol and water were found to interact strongly with the zinc cation, plasticizing the ionic aggregates. At full solvation by glycerol, the zinc atom was found to be coordinated by three glycerol molecules. Dioctylphthalate, acetonitrile, and toluene, which are unable to coordinate to the zinc cation, were found to have a minimal effect on the cation's local structure.

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JO - Journal of Polymer Science Part B: Polymer Physics

JF - Journal of Polymer Science Part B: Polymer Physics

IS - 2

ER -

EXAFS analysis of plasticized zinc‐neutralized sulfonated polystyrene ionomers

Abstract

All Science Journal Classification (ASJC) codes

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