Erratum: Co(salophen)-Catalyzed Aerobic Oxidation of p-Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis (J. Am. Chem. Soc. (2016) 138: 12 (4186-4193) DOI: 10.1021/jacs.6b00254)

Colin W. Anson, Soumya Ghosh, Sharon Hammes-Schiffer, Shannon S. Stahl

Research output: Contribution to journalComment/debatepeer-review

Abstract

Page 4191. We recently identified an error in our data analysis spreadsheet that led to an inadvertent shift in the free energies of certain calculated structures by 1.5 kcal/mol. This shift does not change any of the analysis or conclusions of the paper but alters the quantitative values in the free energy diagram for structures 3 and beyond, shown in Scheme 4 in the main paper. The revised pathway is shown below. Supporting Information, page S12. All entries of the last column (column 6) in Table S7 starting with structure 3 (row 10 and beyond) should be increased by 1.5 kcal/mol, accounting for round-off error. The revised table is provided here.

Original languageEnglish (US)
Pages (from-to)21948-21949
Number of pages2
JournalJournal of the American Chemical Society
Volume142
Issue number52
DOIs
StatePublished - Dec 30 2020

All Science Journal Classification (ASJC) codes

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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