Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex

An Dai; Yinhua Zhou; Andrew L. Shu; Swagat K. Mohapatra; He Wang; Canek Fuentes-Hernandez; Yadong Zhang; Stephen Barlow; Yueh Lin Loo; Seth R. Marder; Bernard Kippelen; Antoine Kahn

doi:10.1002/adfm.201303232

Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex

An Dai, Yinhua Zhou, Andrew L. Shu, Swagat K. Mohapatra, He Wang, Canek Fuentes-Hernandez, Yadong Zhang, Stephen Barlow, Yueh Lin Loo, Seth R. Marder, Bernard Kippelen, Antoine Kahn

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78 Scopus citations

Abstract

Poly(3-hexylthiophene) (P3HT) is p-doped by the new soluble dopant molybdenum tris[1-(methoxycarbonyl)-2-(trifluoromethyl)-ethane-1,2-dithiolene] and investigated via photoemission spectroscopy and transport measurements. Soft-contact transfer lamination of thin layers of the doped P3HT on undoped polymer layers is used to create spatially-confined doped regions, which serve as hole-injection contacts on P3HT diodes. This strategy is then used to create efficient hole-collecting contacts on solution-processed inverted polymer solar cells.

Original language	English (US)
Pages (from-to)	2197-2204
Number of pages	8
Journal	Advanced Functional Materials
Volume	24
Issue number	15
DOIs	https://doi.org/10.1002/adfm.201303232
State	Published - Apr 16 2014

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Condensed Matter Physics
General Materials Science
Electrochemistry
Biomaterials

Keywords

doping
hole extraction layer
lamination
molybdenum complex
polymers

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10.1002/adfm.201303232

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Dai, A., Zhou, Y., Shu, A. L., Mohapatra, S. K., Wang, H., Fuentes-Hernandez, C., Zhang, Y., Barlow, S., Loo, Y. L., Marder, S. R., Kippelen, B., & Kahn, A. (2014). Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex. Advanced Functional Materials, 24(15), 2197-2204. https://doi.org/10.1002/adfm.201303232

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title = "Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex",

abstract = "Poly(3-hexylthiophene) (P3HT) is p-doped by the new soluble dopant molybdenum tris[1-(methoxycarbonyl)-2-(trifluoromethyl)-ethane-1,2-dithiolene] and investigated via photoemission spectroscopy and transport measurements. Soft-contact transfer lamination of thin layers of the doped P3HT on undoped polymer layers is used to create spatially-confined doped regions, which serve as hole-injection contacts on P3HT diodes. This strategy is then used to create efficient hole-collecting contacts on solution-processed inverted polymer solar cells.",

keywords = "doping, hole extraction layer, lamination, molybdenum complex, polymers",

author = "An Dai and Yinhua Zhou and Shu, \{Andrew L.\} and Mohapatra, \{Swagat K.\} and He Wang and Canek Fuentes-Hernandez and Yadong Zhang and Stephen Barlow and Loo, \{Yueh Lin\} and Marder, \{Seth R.\} and Bernard Kippelen and Antoine Kahn",

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month = apr,

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doi = "10.1002/adfm.201303232",

language = "English (US)",

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Dai, A, Zhou, Y, Shu, AL, Mohapatra, SK, Wang, H, Fuentes-Hernandez, C, Zhang, Y, Barlow, S, Loo, YL, Marder, SR, Kippelen, B & Kahn, A 2014, 'Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex', Advanced Functional Materials, vol. 24, no. 15, pp. 2197-2204. https://doi.org/10.1002/adfm.201303232

TY - JOUR

T1 - Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex

AU - Dai, An

AU - Zhou, Yinhua

AU - Shu, Andrew L.

AU - Mohapatra, Swagat K.

AU - Wang, He

AU - Fuentes-Hernandez, Canek

AU - Zhang, Yadong

AU - Barlow, Stephen

AU - Loo, Yueh Lin

AU - Marder, Seth R.

AU - Kippelen, Bernard

AU - Kahn, Antoine

PY - 2014/4/16

Y1 - 2014/4/16

N2 - Poly(3-hexylthiophene) (P3HT) is p-doped by the new soluble dopant molybdenum tris[1-(methoxycarbonyl)-2-(trifluoromethyl)-ethane-1,2-dithiolene] and investigated via photoemission spectroscopy and transport measurements. Soft-contact transfer lamination of thin layers of the doped P3HT on undoped polymer layers is used to create spatially-confined doped regions, which serve as hole-injection contacts on P3HT diodes. This strategy is then used to create efficient hole-collecting contacts on solution-processed inverted polymer solar cells.

AB - Poly(3-hexylthiophene) (P3HT) is p-doped by the new soluble dopant molybdenum tris[1-(methoxycarbonyl)-2-(trifluoromethyl)-ethane-1,2-dithiolene] and investigated via photoemission spectroscopy and transport measurements. Soft-contact transfer lamination of thin layers of the doped P3HT on undoped polymer layers is used to create spatially-confined doped regions, which serve as hole-injection contacts on P3HT diodes. This strategy is then used to create efficient hole-collecting contacts on solution-processed inverted polymer solar cells.

KW - doping

KW - hole extraction layer

KW - lamination

KW - molybdenum complex

KW - polymers

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DO - 10.1002/adfm.201303232

M3 - Article

AN - SCOPUS:84898876702

SN - 1616-301X

VL - 24

SP - 2197

EP - 2204

JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 15

ER -

Enhanced charge-carrier injection and collection via lamination of doped polymer layers p-doped with a solution-processible molybdenum complex

Abstract

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