Enantiopure C 1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation

Sebastien Monfette; Zoë R. Turner; Scott P. Semproni; Paul J. Chirik

doi:10.1021/ja300503k

Enantiopure C ₁-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation

Sebastien Monfette, Zoë R. Turner, Scott P. Semproni, Paul J. Chirik

Chemistry

Research output: Contribution to journal › Article › peer-review

248 Scopus citations

Abstract

Enantiopure C ₁-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.

Original language	English (US)
Pages (from-to)	4561-4564
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	10
DOIs	https://doi.org/10.1021/ja300503k
State	Published - Mar 14 2012

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja300503k

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title = "Enantiopure C 1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation",

abstract = "Enantiopure C 1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.",

author = "Sebastien Monfette and Turner, {Zo{\"e} R.} and Semproni, {Scott P.} and Chirik, {Paul J.}",

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AU - Monfette, Sebastien

AU - Turner, Zoë R.

AU - Semproni, Scott P.

AU - Chirik, Paul J.

PY - 2012/3/14

Y1 - 2012/3/14

N2 - Enantiopure C 1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.

AB - Enantiopure C 1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.

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Enantiopure C ₁-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation

Abstract

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