Electronic structure of SmO and SmO- via slow photoelectron velocity-map imaging spectroscopy and spin-orbit CASPT2 calculations

Marissa L. Weichman, Bess Vlaisavljevich, Jessalyn A. Devine, Nicholas S. Shuman, Shaun G. Ard, Toru Shiozaki, Daniel M. Neumark, Albert A. Viggiano

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Abstract

The chemi-ionization reaction of atomic samarium, Sm + O → SmO+ + e-, has been investigated by the Air Force Research Laboratory as a means to modify local electron density in the ionosphere for reduction of scintillation of high-frequency radio waves. Neutral SmO is a likely unwanted byproduct. The spectroscopy of SmO is of great interest to aid in interpretation of optical emission spectra recorded following atmospheric releases of Sm as part of the Metal Oxide Space Cloud (MOSC) observations. Here, we report a joint experimental and theoretical study of SmO using slow photoelectron velocity-map imaging spectroscopy of cryogenically cooled SmO- anions (cryo-SEVI) and high-level spin-orbit complete active space calculations with corrections from second order perturbation theory (CASPT2). With cryo-SEVI, we measure the electron affinity of SmO to be 1.0581(11) eV and report electronic and vibrational structure of low-lying electronic states of SmO in good agreement with theory and prior experimental work. We also obtain spectra of higher-lying excited states of SmO for direct comparison to the MOSC results.

Original languageEnglish (US)
Article number234311
JournalJournal of Chemical Physics
Volume147
Issue number23
DOIs
StatePublished - Dec 21 2017
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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    Weichman, M. L., Vlaisavljevich, B., Devine, J. A., Shuman, N. S., Ard, S. G., Shiozaki, T., Neumark, D. M., & Viggiano, A. A. (2017). Electronic structure of SmO and SmO- via slow photoelectron velocity-map imaging spectroscopy and spin-orbit CASPT2 calculations. Journal of Chemical Physics, 147(23), [234311]. https://doi.org/10.1063/1.5008423