Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

M. A. Hanratty; E. A. Carter; J. L. Beauchamp; W. A. Goddard; A. J. Illies; M. T. Bowers

doi:10.1016/0009-2614(86)80064-1

Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

M. A. Hanratty, E. A. Carter, J. L. Beauchamp, W. A. Goddard, A. J. Illies, M. T. Bowers

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Abstract

The electronic states of the unsaturated organometallic carbene CrCH₂⁺ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, ⁶B₁, and ⁶A₁ at 0.78 and 0.82 eV respectively, above the ⁴B₁ ground state of CrCH₂⁺.

Original language	English (US)
Pages (from-to)	239-242
Number of pages	4
Journal	Chemical Physics Letters
Volume	123
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(86)80064-1
State	Published - Jan 17 1986
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(86)80064-1

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title = "Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy",

abstract = "The electronic states of the unsaturated organometallic carbene CrCH2+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, 6B1, and 6A1 at 0.78 and 0.82 eV respectively, above the 4B1 ground state of CrCH2+.",

author = "Hanratty, {M. A.} and Carter, {E. A.} and Beauchamp, {J. L.} and Goddard, {W. A.} and Illies, {A. J.} and Bowers, {M. T.}",

year = "1986",

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doi = "10.1016/0009-2614(86)80064-1",

language = "English (US)",

volume = "123",

pages = "239--242",

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T1 - Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

AU - Hanratty, M. A.

AU - Carter, E. A.

AU - Beauchamp, J. L.

AU - Goddard, W. A.

AU - Illies, A. J.

AU - Bowers, M. T.

PY - 1986/1/17

Y1 - 1986/1/17

N2 - The electronic states of the unsaturated organometallic carbene CrCH2+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, 6B1, and 6A1 at 0.78 and 0.82 eV respectively, above the 4B1 ground state of CrCH2+.

AB - The electronic states of the unsaturated organometallic carbene CrCH2+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, 6B1, and 6A1 at 0.78 and 0.82 eV respectively, above the 4B1 ground state of CrCH2+.

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U2 - 10.1016/0009-2614(86)80064-1

DO - 10.1016/0009-2614(86)80064-1

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VL - 123

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EP - 242

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -

Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

Abstract

All Science Journal Classification (ASJC) codes

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