TY - JOUR
T1 - Electrochemical Synthesis of New SbTe Zintl Anions by Catholic Dissolution of Sb2Te3 Electrodes
T2 - Structures of [Sb4Te4]4− and [Sb9Te6]3−
AU - Haushalter, Robert C.
AU - Warren, Christopher J.
AU - Bocarsly, Andrew Bruce
AU - Ho, Douglas M.
PY - 1993/11
Y1 - 1993/11
N2 - A folded Sb4 ring with terminal Te atoms and cluster containing nine Sb atoms and six Te atoms, the respective polyanions [Sb4Te4]4− (1) and [Sb9Te6]3− (2), form concurrently during the catholic dissolution of a Sb2Te3 electrode. This type of electrochemical synthesis certainly extends the repetoire of methods in preparative solid‐state chemistry. ○ = Sb, • = Te. (Figure Presented.)
AB - A folded Sb4 ring with terminal Te atoms and cluster containing nine Sb atoms and six Te atoms, the respective polyanions [Sb4Te4]4− (1) and [Sb9Te6]3− (2), form concurrently during the catholic dissolution of a Sb2Te3 electrode. This type of electrochemical synthesis certainly extends the repetoire of methods in preparative solid‐state chemistry. ○ = Sb, • = Te. (Figure Presented.)
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U2 - 10.1002/anie.199316461
DO - 10.1002/anie.199316461
M3 - Article
AN - SCOPUS:33748236900
SN - 0570-0833
VL - 32
SP - 1646
EP - 1648
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 11
ER -