Electrochemical reactivity of ultra-thin cyanometallate films on electrode surfaces

Georgia A. Arbuckle; Youlin Chen; Carmela Hidalgo-Luangdilok; Andrew Bruce Bocarsly

doi:10.1016/0167-2738(89)90379-2

Electrochemical reactivity of ultra-thin cyanometallate films on electrode surfaces

Georgia A. Arbuckle, Youlin Chen, Carmela Hidalgo-Luangdilok, Andrew Bruce Bocarsly

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Anodization of metal or semiconducting electrodes in the presence of a cyanometallate complex such as ferricyanide leads to the formation of a mixed metal, cyanide bridge, surface complex. Such species form polycrystalline, three-dimensional networks containing channels into which small cations can be intercalated. The thickness of the surface overlayer can be varied from submonolayer to several hundred layers. The surface confined cyanometallate complexes are found to be electroactive in many cases. Both the thermodynamics and dynamics of these species are found to be a strong function of the morphology and crystal geometry of the surface-confined species.

Original language	English (US)
Pages (from-to)	941-945
Number of pages	5
Journal	Solid State Ionics
Volume	32-33
Issue number	PART 2
DOIs	https://doi.org/10.1016/0167-2738(89)90379-2
State	Published - 1989

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/0167-2738(89)90379-2

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title = "Electrochemical reactivity of ultra-thin cyanometallate films on electrode surfaces",

abstract = "Anodization of metal or semiconducting electrodes in the presence of a cyanometallate complex such as ferricyanide leads to the formation of a mixed metal, cyanide bridge, surface complex. Such species form polycrystalline, three-dimensional networks containing channels into which small cations can be intercalated. The thickness of the surface overlayer can be varied from submonolayer to several hundred layers. The surface confined cyanometallate complexes are found to be electroactive in many cases. Both the thermodynamics and dynamics of these species are found to be a strong function of the morphology and crystal geometry of the surface-confined species.",

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T1 - Electrochemical reactivity of ultra-thin cyanometallate films on electrode surfaces

AU - Arbuckle, Georgia A.

AU - Chen, Youlin

AU - Hidalgo-Luangdilok, Carmela

AU - Bocarsly, Andrew Bruce

PY - 1989

Y1 - 1989

N2 - Anodization of metal or semiconducting electrodes in the presence of a cyanometallate complex such as ferricyanide leads to the formation of a mixed metal, cyanide bridge, surface complex. Such species form polycrystalline, three-dimensional networks containing channels into which small cations can be intercalated. The thickness of the surface overlayer can be varied from submonolayer to several hundred layers. The surface confined cyanometallate complexes are found to be electroactive in many cases. Both the thermodynamics and dynamics of these species are found to be a strong function of the morphology and crystal geometry of the surface-confined species.

AB - Anodization of metal or semiconducting electrodes in the presence of a cyanometallate complex such as ferricyanide leads to the formation of a mixed metal, cyanide bridge, surface complex. Such species form polycrystalline, three-dimensional networks containing channels into which small cations can be intercalated. The thickness of the surface overlayer can be varied from submonolayer to several hundred layers. The surface confined cyanometallate complexes are found to be electroactive in many cases. Both the thermodynamics and dynamics of these species are found to be a strong function of the morphology and crystal geometry of the surface-confined species.

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SP - 941

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JO - Solid State Ionics

JF - Solid State Ionics

IS - PART 2

ER -

Electrochemical reactivity of ultra-thin cyanometallate films on electrode surfaces

Abstract

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