Electrochemical reactivity of ultra-thin cyanometallate films on electrode surfaces

Georgia A. Arbuckle, Youlin Chen, Carmela Hidalgo-Luangdilok, Andrew Bruce Bocarsly

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

Anodization of metal or semiconducting electrodes in the presence of a cyanometallate complex such as ferricyanide leads to the formation of a mixed metal, cyanide bridge, surface complex. Such species form polycrystalline, three-dimensional networks containing channels into which small cations can be intercalated. The thickness of the surface overlayer can be varied from submonolayer to several hundred layers. The surface confined cyanometallate complexes are found to be electroactive in many cases. Both the thermodynamics and dynamics of these species are found to be a strong function of the morphology and crystal geometry of the surface-confined species.

Original languageEnglish (US)
Pages (from-to)941-945
Number of pages5
JournalSolid State Ionics
Volume32-33
Issue numberPART 2
DOIs
StatePublished - Jan 1 1989

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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