Abstract
Dicobalt(II) cofacial bisporphyrins anchored by dibenzofuran (DPD) and xanthene (DPX) are efficient electrocatalysts for the four-electron reduction of oxygen to water despite their ca. 4 Å difference in metal-metal distances, suggesting that the considerable longitudinal 'Pac-Man' flexibility of the pillared platforms is the origin for the similar catalytic reactivity of these structurally disparate systems.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1355-1356 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Issue number | 15 |
| DOIs | |
| State | Published - Aug 7 2000 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Catalysis
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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