Elastic properties of crosslinked resorcinol-formaldehyde gels and aerogels

Joachim Gross, George W. Scherer, Cynthia T. Alviso, Richard W. Pekala

Research output: Contribution to journalArticle

39 Scopus citations

Abstract

Resorcinol-formaldehyde (RF) gels with different monomer concentrations were characterized before and after supercritical drying from carbon dioxide in order to determine the influence of the drying process on elastic moduli and structure. Wet gel shear modulus, Young's modulus and Poisson ratio were determined using the beam-bending method. In addition, acoustic shear waves were used to measure the shear modulus of wet gels. The two methods are shown to agree well. During supercritical extraction of the pore liquid the elastic moduli typically increase by a factor of 1.5 to 5 depending on density. Although in general the elastic moduli do not exhibit power-law dependence on density, in the limited density range covered by our experiments scaling exponents of 6.2 for the wet gels and 4.8 for the aerogels are derived. Aging in acetic acid is shown to have no significant impact on gel elastic properties. Wet and dry gels were analyzed for their structural efficiency and the fraction of elastically effective mass increases with density from 8 to 70%.

Original languageEnglish (US)
Pages (from-to)132-142
Number of pages11
JournalJournal of Non-Crystalline Solids
Volume211
Issue number1-2
DOIs
StatePublished - Apr 1997

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

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