Effect of strain and dimensionality on the properties of manganites

C. Adamo, R. Misra, S. A. Denev, A. SenGupta, J. A. Mundy, J. H. Lee, D. A. Muller, V. Gopalan, P. Schiffer, D. G. Schlom

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Strain and dimensional confinement can be used to tune magnetic and ferroelectric properties or enhance device performance. In epitaxial films, the different lattice spacing of an underlying substrate can be used to impose a biaxial strain. We have studied the effect of the substrate-induced biaxial strain on the electrical conductivity and magnetic properties of manganite compounds. Epitaxial (001) La0.7Sr0.3MnO3 thin films have been grown by reactive molecular-beam epitaxy (MBE) on single crystalline substrates, varying the substrate-induced biaxial strain from -2.3% to +3.2%. The strain caused the Curie temperature to decrease by up to 100 K in very good agreement with the predictions of Millis et al. [A. J. Millis, T. Darling, and A. Migliori, J. Appl. Phys. 83, 1588 (1998)]. The effect of dimensional confinement on manganites was also investigated in thin films by synthesizing a superlattice of two formula-unit-thick layers of CaMnO 3 separated by CaO double layers, i.e., the n=2 Ruddlesden-Popper phase Ca3Mn2O7. Magnetization measurements on 30 nm thick (001)-oriented Ca3Mn2O7 thin films grown on (110) YAlO3 substrates by MBE reveal a Neél transition temperature of TN=115 K, similar to bulk Ca 3Mn2O7, but 10 K lower than thick CaMnO 3 films grown on this same substrate.

Original languageEnglish (US)
Title of host publicationPhysics and Technology of High-k Materials 9
PublisherElectrochemical Society Inc.
Pages283-292
Number of pages10
Edition3
ISBN (Electronic)9781607682578
ISBN (Print)9781566779036
DOIs
StatePublished - 2011
Externally publishedYes
Event9th International Symposium on High Dielectric Constant and Other Dielectric Materials for Nanoelectronics and Photonics - 220th ECS Meeting - Boston, MA, United States
Duration: Oct 10 2011Oct 12 2011

Publication series

NameECS Transactions
Number3
Volume41
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

Conference9th International Symposium on High Dielectric Constant and Other Dielectric Materials for Nanoelectronics and Photonics - 220th ECS Meeting
Country/TerritoryUnited States
CityBoston, MA
Period10/10/1110/12/11

All Science Journal Classification (ASJC) codes

  • General Engineering

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