@article{b50c112f362843a3afae23ce9fd0ba96,
title = "Earth-abundant photocatalyst for H2 generation from NH3 with light-emitting diode illumination",
abstract = "Catalysts based on platinum group metals have been a major focus of the chemical industry for decades. We show that plasmonic photocatalysis can transform a thermally unreactive, earth-abundant transition metal into a catalytically active site under illumination. Fe active sites in a Cu-Fe antenna-reactor complex achieve efficiencies very similar to Ru for the photocatalytic decomposition of ammonia under ultrafast pulsed illumination. When illuminated with light-emitting diodes rather than lasers, the photocatalytic efficiencies remain comparable, even when the scale of reaction increases by nearly three orders of magnitude. This result demonstrates the potential for highly efficient, electrically driven production of hydrogen from an ammonia carrier with earth-abundant transition metals.",
author = "Yigao Yuan and Linan Zhou and Hossein Robatjazi and Bao, {Junwei Lucas} and Jingyi Zhou and Aaron Bayles and Lin Yuan and Minghe Lou and Minhan Lou and Suman Khatiwada and Carter, {Emily A.} and Peter Nordlander and Halas, {Naomi J.}",
note = "Funding Information: This article is based upon work supported by the Robert A. Welch foundation under grants C-1220 (N.J.H.) and C-1222 (P.N.) and by the Air Force Office of Scientific Research via the Department of Defense Multidisciplinary University Research Initiative under AFOSR Award FA9550-15-1-0022. Syzygy Plasmonics Inc. is acknowledged for providing the resources for the Gram-scale electrified photocatalysis studies. E.A.C. would like to thank the High-Performance Computing Modernization Program (HPCMP) o the US Department of Defense and Princeton University{\textquoteright}s Terascale Infrastructure for Groundbreaking Research in Engineering and Science (TIGRESS) for providing the computational resources. Publisher Copyright: {\textcopyright} 2022 American Association for the Advancement of Science. All rights reserved.",
year = "2022",
month = nov,
day = "25",
doi = "10.1126/science.abn5636",
language = "English (US)",
volume = "378",
pages = "889--893",
journal = "Science",
issn = "0036-8075",
publisher = "American Association for the Advancement of Science",
number = "6622",
}