Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)

Andrea Goti; Martin F. Semmelhack

doi:10.1016/0022-328X(94)80181-9

Direct synthesis of (η⁶-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η⁵-1-methylpyrrole)chromium(0)

Andrea Goti, Martin F. Semmelhack

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Arene displacement from the title complex occurs under unprecedented mild conditions in neutral media to afford (η⁶-arene)tricarbonylchromium complexes. The process is most effective with heteroaromatic compounds: the first synthesis of a tricarbonyl(η⁶-quinoline)chromium complex and the diastereoselective preparation of a (η⁶-indole) complex derived from L-tryptophan are reported as representative examples.

Original language	English (US)
Pages (from-to)	C4-C7
Journal	Journal of Organometallic Chemistry
Volume	470
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)80181-9
State	Published - May 17 1994

All Science Journal Classification (ASJC) codes

Materials Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Organic Chemistry

Keywords

Arene
Chromium
Indole, Diastereo-selectivity
Pyrrole
Quinoline

Access to Document

10.1016/0022-328X(94)80181-9

Cite this

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title = "Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)",

abstract = "Arene displacement from the title complex occurs under unprecedented mild conditions in neutral media to afford (η6-arene)tricarbonylchromium complexes. The process is most effective with heteroaromatic compounds: the first synthesis of a tricarbonyl(η6-quinoline)chromium complex and the diastereoselective preparation of a (η6-indole) complex derived from L-tryptophan are reported as representative examples.",

keywords = "Arene, Chromium, Indole, Diastereo-selectivity, Pyrrole, Quinoline",

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T1 - Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)

AU - Goti, Andrea

AU - Semmelhack, Martin F.

PY - 1994/5/17

Y1 - 1994/5/17

N2 - Arene displacement from the title complex occurs under unprecedented mild conditions in neutral media to afford (η6-arene)tricarbonylchromium complexes. The process is most effective with heteroaromatic compounds: the first synthesis of a tricarbonyl(η6-quinoline)chromium complex and the diastereoselective preparation of a (η6-indole) complex derived from L-tryptophan are reported as representative examples.

AB - Arene displacement from the title complex occurs under unprecedented mild conditions in neutral media to afford (η6-arene)tricarbonylchromium complexes. The process is most effective with heteroaromatic compounds: the first synthesis of a tricarbonyl(η6-quinoline)chromium complex and the diastereoselective preparation of a (η6-indole) complex derived from L-tryptophan are reported as representative examples.

KW - Arene

KW - Chromium

KW - Indole, Diastereo-selectivity

KW - Pyrrole

KW - Quinoline

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