Direct synthesis of (η6-arene)-tricarbonylchromium complexes by arene displacement from tricarbonyl(η5-1-methylpyrrole)chromium(0)

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Abstract

Arene displacement from the title complex occurs under unprecedented mild conditions in neutral media to afford (η6-arene)tricarbonylchromium complexes. The process is most effective with heteroaromatic compounds: the first synthesis of a tricarbonyl(η6-quinoline)chromium complex and the diastereoselective preparation of a (η6-indole) complex derived from L-tryptophan are reported as representative examples.

Original languageEnglish (US)
JournalJournal of Organometallic Chemistry
Volume470
Issue number1-2
DOIs
StatePublished - May 17 1994

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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