Dinitrogen cleavage with carbon monoxide and silanes

Paul J. Chirik

Dinitrogen cleavage with carbon monoxide and silanes

Chemistry

Research output: Contribution to journal › Conference article › peer-review

Abstract

Addition of carbon monoxide or silanes to zirconium or hafnium compounds with strongly activated dinitrogen ligands results in cleavage of the N-N bond with N-C or N-Si bond formation, respectively. My presentation will focus on the scope of these reactions, the mechanisms by which they operate and their utility in preparing nitrogen-containing organic molecules directly from atmospheric nitrogen.

Original language	English (US)
Journal	ACS National Meeting Book of Abstracts
State	Published - 2011
Event	241st ACS National Meeting and Exposition - Anaheim, CA, United States Duration: Mar 27 2011 → Mar 31 2011

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

Cite this

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title = "Dinitrogen cleavage with carbon monoxide and silanes",

abstract = "Addition of carbon monoxide or silanes to zirconium or hafnium compounds with strongly activated dinitrogen ligands results in cleavage of the N-N bond with N-C or N-Si bond formation, respectively. My presentation will focus on the scope of these reactions, the mechanisms by which they operate and their utility in preparing nitrogen-containing organic molecules directly from atmospheric nitrogen.",

author = "Chirik, {Paul J.}",

year = "2011",

language = "English (US)",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "241st ACS National Meeting and Exposition ; Conference date: 27-03-2011 Through 31-03-2011",

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T1 - Dinitrogen cleavage with carbon monoxide and silanes

AU - Chirik, Paul J.

PY - 2011

Y1 - 2011

N2 - Addition of carbon monoxide or silanes to zirconium or hafnium compounds with strongly activated dinitrogen ligands results in cleavage of the N-N bond with N-C or N-Si bond formation, respectively. My presentation will focus on the scope of these reactions, the mechanisms by which they operate and their utility in preparing nitrogen-containing organic molecules directly from atmospheric nitrogen.

AB - Addition of carbon monoxide or silanes to zirconium or hafnium compounds with strongly activated dinitrogen ligands results in cleavage of the N-N bond with N-C or N-Si bond formation, respectively. My presentation will focus on the scope of these reactions, the mechanisms by which they operate and their utility in preparing nitrogen-containing organic molecules directly from atmospheric nitrogen.

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M3 - Conference article

AN - SCOPUS:80051875833

SN - 0065-7727

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - 241st ACS National Meeting and Exposition

Y2 - 27 March 2011 through 31 March 2011

ER -

Dinitrogen cleavage with carbon monoxide and silanes

Abstract

All Science Journal Classification (ASJC) codes

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