Dielectric properties of TiO2-Nb2O5 crystallographic shear structures

R. J. Cava; J. J. Krajewski; W. F. Peck; G. L. Roberts

doi:10.1557/JMR.1996.0179

Dielectric properties of TiO₂-Nb₂O₅ crystallographic shear structures

R. J. Cava, J. J. Krajewski, W. F. Peck, G. L. Roberts

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The dielectric constants (K) have been measured near ambient temperature for polycrystalline bulk ceramics of the crystallographic shear compounds TiNb₂₄O₆₂, Ti₂Nb₁₀O₂₉, and TiNb₂O₇. These show enhanced K's over Nb₂O₅ and TiO₂, with the 2:10:29 phase displaying an ambient temperature K of approximately 130. We also report the effects of partial substitution of Nb by Ta. In general, the dielectric constants are enhanced for 5-10% Ta substitution, with the detailed behavior differing for the three phases.

Original language	English (US)
Pages (from-to)	1428-1432
Number of pages	5
Journal	Journal of Materials Research
Volume	11
Issue number	6
DOIs	https://doi.org/10.1557/JMR.1996.0179
State	Published - Jun 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1557/JMR.1996.0179

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title = "Dielectric properties of TiO2-Nb2O5 crystallographic shear structures",

abstract = "The dielectric constants (K) have been measured near ambient temperature for polycrystalline bulk ceramics of the crystallographic shear compounds TiNb24O62, Ti2Nb10O29, and TiNb2O7. These show enhanced K's over Nb2O5 and TiO2, with the 2:10:29 phase displaying an ambient temperature K of approximately 130. We also report the effects of partial substitution of Nb by Ta. In general, the dielectric constants are enhanced for 5-10% Ta substitution, with the detailed behavior differing for the three phases.",

author = "Cava, {R. J.} and Krajewski, {J. J.} and Peck, {W. F.} and Roberts, {G. L.}",

year = "1996",

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doi = "10.1557/JMR.1996.0179",

language = "English (US)",

volume = "11",

pages = "1428--1432",

journal = "Journal of Materials Research",

issn = "0884-2914",

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T1 - Dielectric properties of TiO2-Nb2O5 crystallographic shear structures

AU - Cava, R. J.

AU - Krajewski, J. J.

AU - Peck, W. F.

AU - Roberts, G. L.

PY - 1996/6

Y1 - 1996/6

N2 - The dielectric constants (K) have been measured near ambient temperature for polycrystalline bulk ceramics of the crystallographic shear compounds TiNb24O62, Ti2Nb10O29, and TiNb2O7. These show enhanced K's over Nb2O5 and TiO2, with the 2:10:29 phase displaying an ambient temperature K of approximately 130. We also report the effects of partial substitution of Nb by Ta. In general, the dielectric constants are enhanced for 5-10% Ta substitution, with the detailed behavior differing for the three phases.

AB - The dielectric constants (K) have been measured near ambient temperature for polycrystalline bulk ceramics of the crystallographic shear compounds TiNb24O62, Ti2Nb10O29, and TiNb2O7. These show enhanced K's over Nb2O5 and TiO2, with the 2:10:29 phase displaying an ambient temperature K of approximately 130. We also report the effects of partial substitution of Nb by Ta. In general, the dielectric constants are enhanced for 5-10% Ta substitution, with the detailed behavior differing for the three phases.

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DO - 10.1557/JMR.1996.0179

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JO - Journal of Materials Research

JF - Journal of Materials Research

IS - 6

ER -

Dielectric properties of TiO₂-Nb₂O₅ crystallographic shear structures

Abstract

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