Development of an approach to the synthesis of the plakortones

M. F. Semmelhack; Ponnusamy Shanmugam

doi:10.1016/S0040-4039(00)00464-0

Development of an approach to the synthesis of the plakortones

M. F. Semmelhack, Ponnusamy Shanmugam

Chemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A general synthesis of the plakortones has been developed by the synthesis of two key sections, with a focus on Pd(II)-promoted preparation of a cis-fused tetrahydrofuranolactone. The key intermediates were obtained in homochiral form starting from asymmetric epoxidation of an allylic alcohol. (C) 2000 Elsevier Science Ltd.

Original language	English (US)
Pages (from-to)	3567-3571
Number of pages	5
Journal	Tetrahedron Letters
Volume	41
Issue number	19
DOIs	https://doi.org/10.1016/S0040-4039(00)00464-0
State	Published - May 6 2000

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)00464-0

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abstract = "A general synthesis of the plakortones has been developed by the synthesis of two key sections, with a focus on Pd(II)-promoted preparation of a cis-fused tetrahydrofuranolactone. The key intermediates were obtained in homochiral form starting from asymmetric epoxidation of an allylic alcohol. (C) 2000 Elsevier Science Ltd.",

author = "Semmelhack, {M. F.} and Ponnusamy Shanmugam",

note = "Funding Information: Financial support in the form of a grant from the Research Corporation is acknowledged. One of the authors (P.S.) thanks DST (Goverment of India, New Delhi) for awarding a BOYSCAST fellowship.",

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AU - Semmelhack, M. F.

AU - Shanmugam, Ponnusamy

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N2 - A general synthesis of the plakortones has been developed by the synthesis of two key sections, with a focus on Pd(II)-promoted preparation of a cis-fused tetrahydrofuranolactone. The key intermediates were obtained in homochiral form starting from asymmetric epoxidation of an allylic alcohol. (C) 2000 Elsevier Science Ltd.

AB - A general synthesis of the plakortones has been developed by the synthesis of two key sections, with a focus on Pd(II)-promoted preparation of a cis-fused tetrahydrofuranolactone. The key intermediates were obtained in homochiral form starting from asymmetric epoxidation of an allylic alcohol. (C) 2000 Elsevier Science Ltd.

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Development of an approach to the synthesis of the plakortones

Abstract

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