Determining and understanding N-H bond strengths in synthetic nitrogen fixation cycles

Máté J. Bezdek, Iraklis Pappas, Paul J. Chirik

Research output: Chapter in Book/Report/Conference proceedingChapter

7 Scopus citations

Abstract

The fixation of atmospheric dinitrogen to ammonia using molecular catalysts has been a long-standing challenge in homogeneous catalysis and synthetic chemistry. New approaches to this problem may offer more energy-efficient and carbon-neutral routes to this important industrial compound. Despite the ubiquity of ammine, amide, imide and diazenide ligands in coordination chemistry, little thermodynamic data is available for understanding N-H bond strengths in molecules bearing these nitrogenous fragments. This article presents an overview of both computational and experimental approaches for the determination of N-H bond dissociation free energies in a variety of compounds relevant to nitrogen fixation to ammonia. The influence of metal oxidation state, ancillary ligand and identity of the nitrogen donor are highlighted. Implications for future design of molecular systems for the reduction of dinitrogen are discussed.

Original languageEnglish (US)
Title of host publicationTopics in Organometallic Chemistry
PublisherSpringer Verlag
DOIs
StatePublished - Jan 1 2017

Publication series

NameTopics in Organometallic Chemistry
Volume60
ISSN (Print)1436-6002

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry
  • Inorganic Chemistry

Keywords

  • Ammonia
  • Bond dissociation free energy
  • Nitrogen fixation

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    Bezdek, M. J., Pappas, I., & Chirik, P. J. (2017). Determining and understanding N-H bond strengths in synthetic nitrogen fixation cycles. In Topics in Organometallic Chemistry (Topics in Organometallic Chemistry; Vol. 60). Springer Verlag. https://doi.org/10.1007/3418_2016_8