Cyclizations of Enolates onto Aromatic Rings via the Photo-SRN1 Reaction. Preparative and echanistic Aspects

M. F. Semmelhack, Thomas M. Bargar

Research output: Contribution to journalLetter

50 Scopus citations

Abstract

Six-, seven-, eight-, and ten-membered rings are obtained by photostimulated aromatic nucleophilic substitution by enolate anions, but only when internal H-atom transfer from the 7 position of the ketone is blocked, as shown by deuterium labeling.

Original languageEnglish (US)
Pages (from-to)1481-1482
Number of pages2
JournalJournal of Organic Chemistry
Volume42
Issue number8
DOIs
StatePublished - Jan 1 1977
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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