Cs8.5W15O48 and CSW2O6: Members of a new homologous series of cesium tungsten oxides

R. J. Cava, R. S. Roth, T. Siegrist, B. Hessen, J. J. Krajewski, W. F. Peck

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Abstract

The crystal structures of two new reduced cesium tungsten oxides are reported. Along with the previously reported compound Cs6W11O36, they represent several members of a homologous series of layer compounds between the hexagonal tungsten bronze and pyrochlore structure types. The series formula is [A] Cs2nW4n-1O12n, where n - 1 is the number of pyrochlore layers.

Original languageEnglish (US)
Pages (from-to)359-365
Number of pages7
JournalJournal of Solid State Chemistry
Volume103
Issue number2
DOIs
StatePublished - Apr 1993
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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