Cs8.5W15O48 and CSW2O6: Members of a new homologous series of cesium tungsten oxides

R. J. Cava; R. S. Roth; T. Siegrist; B. Hessen; J. J. Krajewski; W. F. Peck

doi:10.1006/jssc.1993.1111

Cs_8.5W₁₅O₄₈ and CSW₂O₆: Members of a new homologous series of cesium tungsten oxides

R. J. Cava, R. S. Roth, T. Siegrist, B. Hessen, J. J. Krajewski, W. F. Peck

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Abstract

The crystal structures of two new reduced cesium tungsten oxides are reported. Along with the previously reported compound Cs₆W₁₁O₃₆, they represent several members of a homologous series of layer compounds between the hexagonal tungsten bronze and pyrochlore structure types. The series formula is [A] Cs_2nW_4n-1O_12n, where n - 1 is the number of pyrochlore layers.

Original language	English (US)
Pages (from-to)	359-365
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	103
Issue number	2
DOIs	https://doi.org/10.1006/jssc.1993.1111
State	Published - Apr 1993
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1006/jssc.1993.1111

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title = "Cs8.5W15O48 and CSW2O6: Members of a new homologous series of cesium tungsten oxides",

abstract = "The crystal structures of two new reduced cesium tungsten oxides are reported. Along with the previously reported compound Cs6W11O36, they represent several members of a homologous series of layer compounds between the hexagonal tungsten bronze and pyrochlore structure types. The series formula is [A] Cs2nW4n-1O12n, where n - 1 is the number of pyrochlore layers.",

author = "Cava, {R. J.} and Roth, {R. S.} and T. Siegrist and B. Hessen and Krajewski, {J. J.} and Peck, {W. F.}",

year = "1993",

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doi = "10.1006/jssc.1993.1111",

language = "English (US)",

volume = "103",

pages = "359--365",

journal = "Journal of Solid State Chemistry",

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TY - JOUR

T1 - Cs8.5W15O48 and CSW2O6

T2 - Members of a new homologous series of cesium tungsten oxides

AU - Cava, R. J.

AU - Roth, R. S.

AU - Siegrist, T.

AU - Hessen, B.

AU - Krajewski, J. J.

AU - Peck, W. F.

PY - 1993/4

Y1 - 1993/4

N2 - The crystal structures of two new reduced cesium tungsten oxides are reported. Along with the previously reported compound Cs6W11O36, they represent several members of a homologous series of layer compounds between the hexagonal tungsten bronze and pyrochlore structure types. The series formula is [A] Cs2nW4n-1O12n, where n - 1 is the number of pyrochlore layers.

AB - The crystal structures of two new reduced cesium tungsten oxides are reported. Along with the previously reported compound Cs6W11O36, they represent several members of a homologous series of layer compounds between the hexagonal tungsten bronze and pyrochlore structure types. The series formula is [A] Cs2nW4n-1O12n, where n - 1 is the number of pyrochlore layers.

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Cs_8.5W₁₅O₄₈ and CSW₂O₆: Members of a new homologous series of cesium tungsten oxides

Abstract

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