TY - JOUR

T1 - Crystallization statistics, thermal history and glass formation

AU - Hopper, R. W.

AU - Scherer, G.

AU - Uhlmann, D. R.

N1 - Funding Information:
Financial support for the present work was provided by the National Aeronautics and Space Administration and by Owens-Illinois Inc., who provided one of the authors (G.S.) with the Owens-Illinois Fellowship in Materials Science. This support is gratefully acknowledged.

PY - 1974/4

Y1 - 1974/4

N2 - The formal theory of transformation kinetics describes the volume fraction of a phase transformed in a given time at a given temperature. The basic concepts are extended for isotropic crystal growth in a material having a known thermal history T(r, t). A crystal distribution function ψ(r, t, R) is defined such that the number of crystallites in a volume dυ at r having radii between R and R + dR at time t is ψ(r, t, R) dυ dR. The function ψ contains essentially complete statistical information about the state of crystallinity of a material. Formal expressions for ψ are obtained. Applications are discussed, including predictions of crystallinity when T(r, t) is known; predictions of glass-forming tendencies; experimental determination of nucleation rates; and the determination of the thermal history of a sample from post mortem crystallinity measurements. As an example, ψ(r, t, R) is calculated for a lunar glass composition subjected to a typical laboratory heat treatment.

AB - The formal theory of transformation kinetics describes the volume fraction of a phase transformed in a given time at a given temperature. The basic concepts are extended for isotropic crystal growth in a material having a known thermal history T(r, t). A crystal distribution function ψ(r, t, R) is defined such that the number of crystallites in a volume dυ at r having radii between R and R + dR at time t is ψ(r, t, R) dυ dR. The function ψ contains essentially complete statistical information about the state of crystallinity of a material. Formal expressions for ψ are obtained. Applications are discussed, including predictions of crystallinity when T(r, t) is known; predictions of glass-forming tendencies; experimental determination of nucleation rates; and the determination of the thermal history of a sample from post mortem crystallinity measurements. As an example, ψ(r, t, R) is calculated for a lunar glass composition subjected to a typical laboratory heat treatment.

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U2 - 10.1016/0022-3093(74)90110-0

DO - 10.1016/0022-3093(74)90110-0

M3 - Article

AN - SCOPUS:0016047248

SN - 0022-3093

VL - 15

SP - 45

EP - 62

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 1

ER -