Crystallization of paraffins with poly(ethylene butene) as revealed by X-ray diffraction

Xuhong Guo; Brian Anthony Pethica; John S. Huang; Robert Krafft Prud'homme

Crystallization of paraffins with poly(ethylene butene) as revealed by X-ray diffraction

Xuhong Guo, Brian Anthony Pethica, John S. Huang, Robert Krafft Prud'homme

Research output: Contribution to journal › Conference article › peer-review

Abstract

XRD measurements for crystals of long chain n-paraffins (C₃₆, C₃₂, and C₂₈) and their mixtures obtained from melt or solutions in decane give well-resolved low angle spectra in the absence of poly(ethylene butane)s (PEB). Added PEB, which disrupt gel formation and improve significantly the fluidity of paraffins solutions in decane, have the effect of disrupt lamellae layering as observed by XRD since the PEB co-crystallizes with the paraffin and the non-crystallizable side ethyl chains in PEB would provide a steric barrier against platelet stacking. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

Original language	English (US)
Journal	ACS National Meeting Book of Abstracts
Volume	229
Issue number	2
State	Published - Aug 3 2005
Event	229th ACS National Meeting - San Diego, CA., United States Duration: Mar 13 2005 → Mar 17 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

Cite this

@article{92db1d22d4f04d938621213959e6abe0,

title = "Crystallization of paraffins with poly(ethylene butene) as revealed by X-ray diffraction",

abstract = "XRD measurements for crystals of long chain n-paraffins (C36, C32, and C28) and their mixtures obtained from melt or solutions in decane give well-resolved low angle spectra in the absence of poly(ethylene butane)s (PEB). Added PEB, which disrupt gel formation and improve significantly the fluidity of paraffins solutions in decane, have the effect of disrupt lamellae layering as observed by XRD since the PEB co-crystallizes with the paraffin and the non-crystallizable side ethyl chains in PEB would provide a steric barrier against platelet stacking. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).",

author = "Xuhong Guo and Pethica, {Brian Anthony} and Huang, {John S.} and Prud'homme, {Robert Krafft}",

year = "2005",

month = aug,

day = "3",

language = "English (US)",

volume = "229",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

number = "2",

note = "229th ACS National Meeting ; Conference date: 13-03-2005 Through 17-03-2005",

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TY - JOUR

T1 - Crystallization of paraffins with poly(ethylene butene) as revealed by X-ray diffraction

AU - Guo, Xuhong

AU - Pethica, Brian Anthony

AU - Huang, John S.

AU - Prud'homme, Robert Krafft

PY - 2005/8/3

Y1 - 2005/8/3

N2 - XRD measurements for crystals of long chain n-paraffins (C36, C32, and C28) and their mixtures obtained from melt or solutions in decane give well-resolved low angle spectra in the absence of poly(ethylene butane)s (PEB). Added PEB, which disrupt gel formation and improve significantly the fluidity of paraffins solutions in decane, have the effect of disrupt lamellae layering as observed by XRD since the PEB co-crystallizes with the paraffin and the non-crystallizable side ethyl chains in PEB would provide a steric barrier against platelet stacking. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

AB - XRD measurements for crystals of long chain n-paraffins (C36, C32, and C28) and their mixtures obtained from melt or solutions in decane give well-resolved low angle spectra in the absence of poly(ethylene butane)s (PEB). Added PEB, which disrupt gel formation and improve significantly the fluidity of paraffins solutions in decane, have the effect of disrupt lamellae layering as observed by XRD since the PEB co-crystallizes with the paraffin and the non-crystallizable side ethyl chains in PEB would provide a steric barrier against platelet stacking. This is an abstract of a paper presented at the 229th ACS National Meeting (San Diego, CA 3/13-17/2005).

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M3 - Conference article

AN - SCOPUS:22744445984

SN - 0065-7727

VL - 229

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

IS - 2

T2 - 229th ACS National Meeting

Y2 - 13 March 2005 through 17 March 2005

ER -

Crystallization of paraffins with poly(ethylene butene) as revealed by X-ray diffraction

Abstract

All Science Journal Classification (ASJC) codes

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