Crystal growth of CsCl-type Yb0.24Sn0.76Ru

T. Klimczuk; C. H. Wang; Q. Xu; J. Lawrence; T. Durakiewicz; F. Ronning; A. Llobet; E. D. Bauer; J. C. Griveau; W. Sadowski; H. W. Zandbergen; J. D. Thompson; R. J. Cava

doi:10.1016/j.jcrysgro.2010.10.045

Crystal growth of CsCl-type Yb_0.24Sn_0.76Ru

T. Klimczuk
, C. H. Wang
, Q. Xu
, J. Lawrence
, T. Durakiewicz
, F. Ronning
, A. Llobet
, E. D. Bauer
, J. C. Griveau
, W. Sadowski
, H. W. Zandbergen
, J. D. Thompson
, R. J. Cava

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The YbRuSn ternary system was investigated and a new material, Yb _0.24Sn_0.76Ru, with a simple cubic crystal structure, was discovered. Yb_0.24Sn_0.76Ru has a smaller lattice parameter a=3.217(4) Å, than its isostructural YbRu analogue (a=3.360 Å). Both X-ray diffraction and electron microscopy techniques were used to refine the crystal structure of Yb_0.24Sn_0.76Ru. It was found that a new compound forms in the CsCl structure, with Ru on the 1a site and a (Yb, Sn) mixture on site 1b. The XRD Rietveld analysis provides the occupation of Yb equal to 0.24, in agreement with the single crystal nano-electron diffraction refinement, which gives the occupation 0.21.

Original language	English (US)
Pages (from-to)	1005-1008
Number of pages	4
Journal	Journal of Crystal Growth
Volume	318
Issue number	1
DOIs	https://doi.org/10.1016/j.jcrysgro.2010.10.045
State	Published - Mar 1 2011

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Inorganic Chemistry
Materials Chemistry

Keywords

A1. X-ray diffraction
A2. Single crystal growth
B1. Rare earth compounds

Access to Document

10.1016/j.jcrysgro.2010.10.045

Cite this

@article{73518068db604696a07b63826c1a8c82,

title = "Crystal growth of CsCl-type Yb0.24Sn0.76Ru",

abstract = "The YbRuSn ternary system was investigated and a new material, Yb 0.24Sn0.76Ru, with a simple cubic crystal structure, was discovered. Yb0.24Sn0.76Ru has a smaller lattice parameter a=3.217(4) {\AA}, than its isostructural YbRu analogue (a=3.360 {\AA}). Both X-ray diffraction and electron microscopy techniques were used to refine the crystal structure of Yb0.24Sn0.76Ru. It was found that a new compound forms in the CsCl structure, with Ru on the 1a site and a (Yb, Sn) mixture on site 1b. The XRD Rietveld analysis provides the occupation of Yb equal to 0.24, in agreement with the single crystal nano-electron diffraction refinement, which gives the occupation 0.21.",

keywords = "A1. X-ray diffraction, A2. Single crystal growth, B1. Rare earth compounds",

author = "T. Klimczuk and Wang, \{C. H.\} and Q. Xu and J. Lawrence and T. Durakiewicz and F. Ronning and A. Llobet and Bauer, \{E. D.\} and Griveau, \{J. C.\} and W. Sadowski and Zandbergen, \{H. W.\} and Thompson, \{J. D.\} and Cava, \{R. J.\}",

note = "Funding Information: The authors acknowledge financial support from the European Union under the Framework 6 program under a contract for an Integrated Infrastructure Initiative; reference 026019 ESTEEM . Work at Los Alamos and Princeton was performed under the auspices of the US Department of Energy, Office of Science. We thank Bert Cremer for the use of the SEM microscope. Copyright: Copyright 2011 Elsevier B.V., All rights reserved.",

year = "2011",

month = mar,

day = "1",

doi = "10.1016/j.jcrysgro.2010.10.045",

language = "English (US)",

volume = "318",

pages = "1005--1008",

journal = "Journal of Crystal Growth",

issn = "0022-0248",

publisher = "Elsevier B.V.",

number = "1",

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T1 - Crystal growth of CsCl-type Yb0.24Sn0.76Ru

AU - Klimczuk, T.

AU - Wang, C. H.

AU - Xu, Q.

AU - Lawrence, J.

AU - Durakiewicz, T.

AU - Ronning, F.

AU - Llobet, A.

AU - Bauer, E. D.

AU - Griveau, J. C.

AU - Sadowski, W.

AU - Zandbergen, H. W.

AU - Thompson, J. D.

AU - Cava, R. J.

N1 - Funding Information: The authors acknowledge financial support from the European Union under the Framework 6 program under a contract for an Integrated Infrastructure Initiative; reference 026019 ESTEEM . Work at Los Alamos and Princeton was performed under the auspices of the US Department of Energy, Office of Science. We thank Bert Cremer for the use of the SEM microscope. Copyright: Copyright 2011 Elsevier B.V., All rights reserved.

PY - 2011/3/1

Y1 - 2011/3/1

N2 - The YbRuSn ternary system was investigated and a new material, Yb 0.24Sn0.76Ru, with a simple cubic crystal structure, was discovered. Yb0.24Sn0.76Ru has a smaller lattice parameter a=3.217(4) Å, than its isostructural YbRu analogue (a=3.360 Å). Both X-ray diffraction and electron microscopy techniques were used to refine the crystal structure of Yb0.24Sn0.76Ru. It was found that a new compound forms in the CsCl structure, with Ru on the 1a site and a (Yb, Sn) mixture on site 1b. The XRD Rietveld analysis provides the occupation of Yb equal to 0.24, in agreement with the single crystal nano-electron diffraction refinement, which gives the occupation 0.21.

AB - The YbRuSn ternary system was investigated and a new material, Yb 0.24Sn0.76Ru, with a simple cubic crystal structure, was discovered. Yb0.24Sn0.76Ru has a smaller lattice parameter a=3.217(4) Å, than its isostructural YbRu analogue (a=3.360 Å). Both X-ray diffraction and electron microscopy techniques were used to refine the crystal structure of Yb0.24Sn0.76Ru. It was found that a new compound forms in the CsCl structure, with Ru on the 1a site and a (Yb, Sn) mixture on site 1b. The XRD Rietveld analysis provides the occupation of Yb equal to 0.24, in agreement with the single crystal nano-electron diffraction refinement, which gives the occupation 0.21.

KW - A1. X-ray diffraction

KW - A2. Single crystal growth

KW - B1. Rare earth compounds

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