Correction to: Nickel-catalyzed enantioselective reductive cross-coupling of styrenyl aziridines (Journal of the American Chemical Society (2017) 139 (5688-5691) DOI: 10.1021/jacs.7b03448)

Brian P. Woods, Manuel Orlandi, Chung Yang Dennis Huang, Matthew S. Sigman, Abigail G. Doyle

Research output: Contribution to journalComment/debate

1 Scopus citations

Abstract

Table of Contents. The enantiomer of the BiOx ligand that delivers the indicated absolute configuration of product is (R,R)-(4-heptyl)BiOx. The corrected graphic is shown below: Page 5690. The absolute configuration of ligand L7 (4-heptyl- BiOx) was misassigned. The updated assignment requires corrections to Figure 2 and Table 3. The (S)-enantiomer of cross-coupled product 7 is obtained using the (S,S)-series of BiOx ligands. The corrected Figure 2 is given here. Page 5690. (R,R)-L7, not (S,S)-L7, was used for the scope studies in Table 3. The corrected Table 3 is shown here. We thank the Reisman laboratory for sharing information leading to this reassignment. (Figure Presented). Supporting Information. Page S2. The (R,R)- not the (S,S)-BiOx ligands L7-L9 were used for the studies in Figure S1. Pages S4 and S5. (R,R)-L7, not (S,S)-L7, was used for the scope studies in Tables S1, S2, and S4. Page S8. The (S)-enantiomer of cross-coupled product 7 is obtained using the (S,S)-L7 ligand in Scheme S5. Pages S12 and S13. The absolute configurations of structures S2-S5 have been corrected.

Original languageEnglish (US)
Pages (from-to)7744-7745
Number of pages2
JournalJournal of the American Chemical Society
Volume140
Issue number24
DOIs
StatePublished - Jun 20 2018

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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