Configuration mixing effects on molecular dipole transition moments

Michael Oppenheimer, K. Kirby Docken

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

The behavior of dipole transition matrix elements between adiabatic eigenstates of diatomic molecules is explored in the region of large configuration mixing. It is demonstrated that the matrix element has a lorentzian shape as a function of internuclear distance. The effect of this shape on the spectrum of LiH is investigated. The strong enhancement of the dipole transition moment in the interaction region is suggested as a source for nonthermal population distributions and laser radiation in alkali diatomics and hydrides.

Original languageEnglish (US)
Pages (from-to)349-352
Number of pages4
JournalChemical Physics Letters
Volume29
Issue number3
DOIs
StatePublished - Dec 1 1974
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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