Dense polyhedron packings are useful models of a variety of condensed matter and biological systems and have intrigued scientists and mathematicians for centuries. Here, we analytically construct the densest known packing of truncated tetrahedra with a remarkably high packing fraction 207208 0.995192, which is amazingly close to unity and strongly implies its optimality. This construction is based on a generalized organizing principle for polyhedra lacking central symmetry that we introduce here. The holes in the putative optimal packing are perfect tetrahedra, which leads to a new tessellation of space by truncated tetrahedra and tetrahedra. Its packing characteristics and equilibrium melting properties as the system undergoes decompression are discussed.
|Original language||English (US)|
|Journal||Journal of Chemical Physics|
|State||Published - Oct 21 2011|
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry