Cobalt Catalyzed Z -Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

Keyphrases

• Cobalt-catalyzed 100%
• Terminal Alkynes 100%
• Z-selectivity 100%
• Hydroboration 100%
• Esters 66%
• Bis(imino)pyridine 33%
• Relative Rate 33%
• Catalytic Reaction 33%
• Selective Insertion 33%
• Imines 33%
• Precious Metal Catalyst 33%
• Cobalt Pre-catalyst 33%
• Intermediate Support 33%
• Vinylboronates 33%
• Activation Rate 33%
• Alkynylboronates 33%
• Catalytic Hydroboration 33%
• Metal Vinylidene 33%
• Stereochemical Outcome 33%
• Hydrogen Bond (H-bond) 33%
• Deuterium Labelling Studies 33%

Chemistry

• Cobalt 100%
• Alkyne 100%
• Hydroboration 100%
• Catalytic Reaction 33%
• Metal Catalyst 33%
• pre-catalyst 33%
• Noble Metal 33%
• Imine 33%
• Deuterium 33%
• Pyridine 33%