Co-ordination of styrene oxide to a sterically hindered ruthenium(II) porphyrin

John Taylor Groves; Yuanzhang Han; Donna Van Engen

doi:10.1039/C39900000436

Co-ordination of styrene oxide to a sterically hindered ruthenium(II) porphyrin

John Taylor Groves, Yuanzhang Han, Donna Van Engen

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Abstract

The crystal and molecular structure of an adduct of styrene oxide and tetra-(2, 6-dichlorophenyl)porphyrinato(carbonyl)ruthenium(II) reveals co-ordination of the epoxide ring at 49° with respect to the mean porphyrin plane such that there are close non-bonded interactions between the oxirane protons and a porphyrin pyrrole ring and between the styrene oxide phenyl carbons and one chlorine.

Original language	English (US)
Pages (from-to)	436-437
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	5
DOIs	https://doi.org/10.1039/C39900000436
State	Published - Dec 1 1990

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39900000436

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title = "Co-ordination of styrene oxide to a sterically hindered ruthenium(II) porphyrin",

abstract = "The crystal and molecular structure of an adduct of styrene oxide and tetra-(2, 6-dichlorophenyl)porphyrinato(carbonyl)ruthenium(II) reveals co-ordination of the epoxide ring at 49° with respect to the mean porphyrin plane such that there are close non-bonded interactions between the oxirane protons and a porphyrin pyrrole ring and between the styrene oxide phenyl carbons and one chlorine.",

author = "Groves, {John Taylor} and Yuanzhang Han and {Van Engen}, Donna",

year = "1990",

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doi = "10.1039/C39900000436",

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publisher = "Royal Society of Chemistry",

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AU - Groves, John Taylor

AU - Han, Yuanzhang

AU - Van Engen, Donna

PY - 1990/12/1

Y1 - 1990/12/1

N2 - The crystal and molecular structure of an adduct of styrene oxide and tetra-(2, 6-dichlorophenyl)porphyrinato(carbonyl)ruthenium(II) reveals co-ordination of the epoxide ring at 49° with respect to the mean porphyrin plane such that there are close non-bonded interactions between the oxirane protons and a porphyrin pyrrole ring and between the styrene oxide phenyl carbons and one chlorine.

AB - The crystal and molecular structure of an adduct of styrene oxide and tetra-(2, 6-dichlorophenyl)porphyrinato(carbonyl)ruthenium(II) reveals co-ordination of the epoxide ring at 49° with respect to the mean porphyrin plane such that there are close non-bonded interactions between the oxirane protons and a porphyrin pyrrole ring and between the styrene oxide phenyl carbons and one chlorine.

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JF - Journal of the Chemical Society, Chemical Communications

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Co-ordination of styrene oxide to a sterically hindered ruthenium(II) porphyrin

Abstract

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