Charge transfer between plastocyanin and iron hexacyanide

K. C. Cho; Robert H. Austin

doi:10.1063/1.446842

Charge transfer between plastocyanin and iron hexacyanide

K. C. Cho, Robert H. Austin

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The electron exchange kinetics between plastocyanin and iron hexacyanide has been studied by laser temperature jump. A general kinetic scheme assuming weak binding of the iron hexacyanide to a distant (10 Å) site has been used to extract intrinsic exchange rates of 68±20 s^-1 for Cu(2+) to Cu(1+) reduction, and 200±100 s^-1 for the reverse reaction. These intrinsic rates have been compared to simple nonadiabatic tunneling theories and found to be in reasonable agreement.

Original language	English (US)
Pages (from-to)	1131-1134
Number of pages	4
Journal	The Journal of chemical physics
Volume	80
Issue number	3
DOIs	https://doi.org/10.1063/1.446842
State	Published - 1983

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.446842

Cite this

@article{ec23193243e5483abb6e02f1ef5971ee,

title = "Charge transfer between plastocyanin and iron hexacyanide",

abstract = "The electron exchange kinetics between plastocyanin and iron hexacyanide has been studied by laser temperature jump. A general kinetic scheme assuming weak binding of the iron hexacyanide to a distant (10 {\AA}) site has been used to extract intrinsic exchange rates of 68±20 s-1 for Cu(2+) to Cu(1+) reduction, and 200±100 s-1 for the reverse reaction. These intrinsic rates have been compared to simple nonadiabatic tunneling theories and found to be in reasonable agreement.",

author = "Cho, {K. C.} and Austin, {Robert H.}",

year = "1983",

doi = "10.1063/1.446842",

language = "English (US)",

volume = "80",

pages = "1131--1134",

journal = "The Journal of chemical physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "3",

}

TY - JOUR

T1 - Charge transfer between plastocyanin and iron hexacyanide

AU - Cho, K. C.

AU - Austin, Robert H.

PY - 1983

Y1 - 1983

N2 - The electron exchange kinetics between plastocyanin and iron hexacyanide has been studied by laser temperature jump. A general kinetic scheme assuming weak binding of the iron hexacyanide to a distant (10 Å) site has been used to extract intrinsic exchange rates of 68±20 s-1 for Cu(2+) to Cu(1+) reduction, and 200±100 s-1 for the reverse reaction. These intrinsic rates have been compared to simple nonadiabatic tunneling theories and found to be in reasonable agreement.

AB - The electron exchange kinetics between plastocyanin and iron hexacyanide has been studied by laser temperature jump. A general kinetic scheme assuming weak binding of the iron hexacyanide to a distant (10 Å) site has been used to extract intrinsic exchange rates of 68±20 s-1 for Cu(2+) to Cu(1+) reduction, and 200±100 s-1 for the reverse reaction. These intrinsic rates have been compared to simple nonadiabatic tunneling theories and found to be in reasonable agreement.

UR - http://www.scopus.com/inward/record.url?scp=36549099983&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=36549099983&partnerID=8YFLogxK

U2 - 10.1063/1.446842

DO - 10.1063/1.446842

M3 - Article

AN - SCOPUS:36549099983

SN - 0021-9606

VL - 80

SP - 1131

EP - 1134

JO - The Journal of chemical physics

JF - The Journal of chemical physics

IS - 3

ER -

Charge transfer between plastocyanin and iron hexacyanide

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this