Cementation of colloidal particles on electrodes in a galvanic microreactor

Linda Jan, Christian Punckt, Ilhan A. Aksay

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

We have studied the processes leading to the cementation of colloidal particles during their autonomous assembly on corroding copper electrodes within a Cu-Au galvanic microreactor. We determined the onset of particle immobilization through particle tracking, monitored the dissolution of copper as well as the deposition of insoluble products of the corrosion reactions in situ, and showed that particle immobilization initiated after reaction products (RPs) began to deposit on the electrode substrate. We further demonstrated that the time and the extent of RP precipitation and thus the strength of the particle-substrate bond could be tuned by varying the amount of copper in the system and the microreactor pH. The ability to cement colloidal particles at locations undergoing corrosion illustrates that the studied colloidal assembly approach holds potential for applications in dynamic material property adaptation.

Original languageEnglish (US)
Pages (from-to)6346-6353
Number of pages8
JournalACS Applied Materials and Interfaces
Volume5
Issue number13
DOIs
StatePublished - Jul 10 2013

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Keywords

  • cementation
  • colloidal particles
  • electrochemistry
  • galvanic corrosion
  • material processing
  • reaction products

Fingerprint Dive into the research topics of 'Cementation of colloidal particles on electrodes in a galvanic microreactor'. Together they form a unique fingerprint.

  • Cite this