Catalytically active metal oxide-supported rhodium hydride complexes

Michael D. Ward; Jeffrey Schwartz

doi:10.1016/0304-5102(81)87027-7

Catalytically active metal oxide-supported rhodium hydride complexes

Michael D. Ward, Jeffrey Schwartz

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Abstract

Well defined metal oxide-supported rhodium hydride complexes were prepared in which the Rh is covalently anchored to the support through a rhodiumoxygen bond. The various complexes differ in their ligand environments and, as a result, exhibit markedly different behavior as olefin hydrogenation catalysts. Spectral characterization of these complexes was performed and rhodium hydrides were verified as the active species for olefin hydrogenation. Reactivity patterns for these complexes are compared with analogues in homogeneous systems.

Original language	English (US)
Pages (from-to)	397-407
Number of pages	11
Journal	Journal of Molecular Catalysis
Volume	11
Issue number	2-3
DOIs	https://doi.org/10.1016/0304-5102(81)87027-7
State	Published - 1981

All Science Journal Classification (ASJC) codes

General Engineering

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10.1016/0304-5102(81)87027-7

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title = "Catalytically active metal oxide-supported rhodium hydride complexes",

abstract = "Well defined metal oxide-supported rhodium hydride complexes were prepared in which the Rh is covalently anchored to the support through a rhodiumoxygen bond. The various complexes differ in their ligand environments and, as a result, exhibit markedly different behavior as olefin hydrogenation catalysts. Spectral characterization of these complexes was performed and rhodium hydrides were verified as the active species for olefin hydrogenation. Reactivity patterns for these complexes are compared with analogues in homogeneous systems.",

author = "Ward, {Michael D.} and Jeffrey Schwartz",

year = "1981",

doi = "10.1016/0304-5102(81)87027-7",

language = "English (US)",

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T1 - Catalytically active metal oxide-supported rhodium hydride complexes

AU - Ward, Michael D.

AU - Schwartz, Jeffrey

PY - 1981

Y1 - 1981

N2 - Well defined metal oxide-supported rhodium hydride complexes were prepared in which the Rh is covalently anchored to the support through a rhodiumoxygen bond. The various complexes differ in their ligand environments and, as a result, exhibit markedly different behavior as olefin hydrogenation catalysts. Spectral characterization of these complexes was performed and rhodium hydrides were verified as the active species for olefin hydrogenation. Reactivity patterns for these complexes are compared with analogues in homogeneous systems.

AB - Well defined metal oxide-supported rhodium hydride complexes were prepared in which the Rh is covalently anchored to the support through a rhodiumoxygen bond. The various complexes differ in their ligand environments and, as a result, exhibit markedly different behavior as olefin hydrogenation catalysts. Spectral characterization of these complexes was performed and rhodium hydrides were verified as the active species for olefin hydrogenation. Reactivity patterns for these complexes are compared with analogues in homogeneous systems.

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U2 - 10.1016/0304-5102(81)87027-7

DO - 10.1016/0304-5102(81)87027-7

M3 - Article

AN - SCOPUS:0019560838

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EP - 407

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

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ER -

Catalytically active metal oxide-supported rhodium hydride complexes

Abstract

All Science Journal Classification (ASJC) codes

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