Catalytic tandem oxy-palladation and vinylation

M. F. Semmelhack; W. R. Epa

doi:10.1016/S0040-4039(00)79288-4

Catalytic tandem oxy-palladation and vinylation

M. F. Semmelhack
, W. R. Epa

Chemistry

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

Original language	English (US)
Pages (from-to)	7205-7208
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4039(00)79288-4
State	Published - Nov 5 1993

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)79288-4

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title = "Catalytic tandem oxy-palladation and vinylation",

abstract = "Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.",

author = "Semmelhack, \{M. F.\} and Epa, \{W. R.\}",

year = "1993",

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doi = "10.1016/S0040-4039(00)79288-4",

language = "English (US)",

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journal = "Tetrahedron Letters",

issn = "0040-4039",

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T1 - Catalytic tandem oxy-palladation and vinylation

AU - Semmelhack, M. F.

AU - Epa, W. R.

PY - 1993/11/5

Y1 - 1993/11/5

N2 - Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

AB - Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

UR - https://www.scopus.com/pages/publications/0027360182

UR - https://www.scopus.com/pages/publications/0027360182#tab=citedBy

U2 - 10.1016/S0040-4039(00)79288-4

DO - 10.1016/S0040-4039(00)79288-4

M3 - Article

AN - SCOPUS:0027360182

SN - 0040-4039

VL - 34

SP - 7205

EP - 7208

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

Catalytic tandem oxy-palladation and vinylation

Abstract

All Science Journal Classification (ASJC) codes

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