Catalytic tandem oxy-palladation and vinylation

M. F. Semmelhack; W. R. Epa

doi:10.1016/S0040-4039(00)79288-4

Catalytic tandem oxy-palladation and vinylation

M. F. Semmelhack, W. R. Epa

Chemistry

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

Original language	English (US)
Pages (from-to)	7205-7208
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4039(00)79288-4
State	Published - Nov 5 1993

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)79288-4

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title = "Catalytic tandem oxy-palladation and vinylation",

abstract = "Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.",

author = "Semmelhack, {M. F.} and Epa, {W. R.}",

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AU - Epa, W. R.

PY - 1993/11/5

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N2 - Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

AB - Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

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U2 - 10.1016/S0040-4039(00)79288-4

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M3 - Article

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EP - 7208

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 45

ER -

Catalytic tandem oxy-palladation and vinylation

Abstract

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