Catalytic tandem oxy-palladation and vinylation

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Abstract

Intramolecular oxy-palladation of hydroxy-alkenes leads to organo-Pd(II) intermediates which can be trapped by alkenes in chain extension by vinyl substitution; catalysis is efficient using a reoxidation system but the process is limited to substrates which cannot undergo β-hydride elimination from the organo-Pd(II) intermediate.

Original languageEnglish (US)
Pages (from-to)7205-7208
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number45
DOIs
StatePublished - Nov 5 1993

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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