Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer

Keyphrases

• Amides 100%
• Proton-coupled Electron Transfer 100%
• Carbon-hydrogen Bond 100%
• Catalytic Alkylation 100%
• Amidyl Radicals 60%
• N-H Bond 40%
• Hydrogen Atom Transfer 40%
• Carbon-carbon Bond 40%
• N-alkylamide 40%
• Molecular Hydrogen 20%
• Amines 20%
• Excited States 20%
• Hydrogen Abstraction 20%
• Olefins 20%
• Amination 20%
• Radical Intermediates 20%
• Motivation 20%
• Proton 20%
• Alkylation 20%
• Hydrogen Radical 20%
• Phosphate 20%
• Homolysis 20%
• Organic Functional Groups 20%
• Homolytic 20%
• Natural Products 20%
• New Carbon 20%
• Hydrogen Atom 20%
• Activating Groups 20%
• Transfer Approach 20%
• Structural Elaboration 20%
• Direct Construction 20%
• Pharmaceutical Products 20%
• Aliphatic Carbon 20%
• Iridium Photocatalyst 20%
• Radical Alkylation 20%
• Hydrogen Atom Transfer Catalyst 20%
• Pre-functionalization 20%

Chemistry

• Carboxamide 100%
• Hydrogen Bonding 100%
• Catalytic Alkylation 100%
• Electron Transport 100%
• Hydrogen 57%
• Hydrogen Atom 42%
• Alkylation 28%
• Excited State 14%
• Base 14%
• Alkene 14%
• Iridium 14%
• Catalysis 14%
• Photocatalyst 14%
• formation 14%
• Natural Product 14%
• amination 14%
• Catalyst 14%
• Nitrogen 14%
• Amine 14%