TY - JOUR
T1 - Catalyst layer ink interactions that affect coatability
AU - Dixit, Marm B.
AU - Harkey, Brice A.
AU - Shen, Fengyu
AU - Hatzell, Kelsey B.
N1 - Funding Information:
The authors were supported by the National Science Foundation under grant No. 1727863. K.B.H acknowledges support from the Ralph E. Powe Junior Faculty Enhancement Award from ORAU. The authors acknowledge the Vanderbilt Institute of Nanoscience and Engineering (VINSE) for access to their shared characterization facilities.
Publisher Copyright:
© The Author(s) 2018.
PY - 2018
Y1 - 2018
N2 - Catalyst layer inks are examples of biphasic material systems composed of a solid material, a polymer, and a solvent. Nanoscale interactions between the individual constituents can alter macroscopic properties that are relevant for coating and manufacturing processes (i.e. viscosity, surface tension, aggregation, and rheology). Control over these macroscale properties are important for controlled electrode formation during scalable roll-to-roll manufacturing. The underlying interactions include polymer|particle, particle|solvent, and polymer|solvent interactions. In this work we systematically investigate polymer|particle interactions via studying a range of formulated inks composed of different solvents (methanol, isopropyl alcohol, octanol, and water), varying polymer loadings, and particles with different surface charges. Ink aging is also addressed and over short time periods (<1 hr shelf life) the addition of a perfluorosulfonic acid ionomer was shown to stabilize the ink and also decrease the aggregation size. However, over long time periods (168 hrs) the aggregation size is independent of polymer loading, and approaches a steady state aggregation size around 350 nm. This equilibrium point suggests that the polymer is free to diffuse, adsorb, and relax within the excluded volume region. Furthermore, these results suggest that primary aggregates can be broken up with the addition of very low polymer loadings (15% I:C). A semi-empirical model is used to describe polymer|particle interactions within the ink, and the polymer coverage at the surface of the carbon was found to be the most sensitive parameter dictating ink stability. Finally, coating and rheology experiments are completed on all inks.
AB - Catalyst layer inks are examples of biphasic material systems composed of a solid material, a polymer, and a solvent. Nanoscale interactions between the individual constituents can alter macroscopic properties that are relevant for coating and manufacturing processes (i.e. viscosity, surface tension, aggregation, and rheology). Control over these macroscale properties are important for controlled electrode formation during scalable roll-to-roll manufacturing. The underlying interactions include polymer|particle, particle|solvent, and polymer|solvent interactions. In this work we systematically investigate polymer|particle interactions via studying a range of formulated inks composed of different solvents (methanol, isopropyl alcohol, octanol, and water), varying polymer loadings, and particles with different surface charges. Ink aging is also addressed and over short time periods (<1 hr shelf life) the addition of a perfluorosulfonic acid ionomer was shown to stabilize the ink and also decrease the aggregation size. However, over long time periods (168 hrs) the aggregation size is independent of polymer loading, and approaches a steady state aggregation size around 350 nm. This equilibrium point suggests that the polymer is free to diffuse, adsorb, and relax within the excluded volume region. Furthermore, these results suggest that primary aggregates can be broken up with the addition of very low polymer loadings (15% I:C). A semi-empirical model is used to describe polymer|particle interactions within the ink, and the polymer coverage at the surface of the carbon was found to be the most sensitive parameter dictating ink stability. Finally, coating and rheology experiments are completed on all inks.
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U2 - 10.1149/2.0191805jes
DO - 10.1149/2.0191805jes
M3 - Article
AN - SCOPUS:85046666319
SN - 0013-4651
VL - 165
SP - F264-F271
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
IS - 5
ER -