Carboxylation of an ansa-zirconocene dinitrogen complex: Regiospecific hydrazine synthesis from N₂ and CO₂

Keyphrases

• Dinitrogen Complex 100%
• Ansa-zirconocene 100%
• Carboxylation 100%
• Regiospecific 100%
• Hydrazine Synthesis 100%
• Zirconia 66%
• Hydrazine 66%
• Carbon Dioxide 33%
• Heterocumulene 33%
• Ansa 33%
• Dinitrogen 33%
• Trisubstituted 33%
• Cyclopentadienyl Ligands 33%
• Carbon Bond 33%
• C2 Symmetry 33%
• Selective Insertion 33%
• Bond-forming 33%
• Tert-butyl 33%
• Regiochemistry 33%
• New Nitrogen 33%
• Stereochemistry 33%
• C2-symmetric 33%
• Tetra-substituted 33%
• Sterically Demanding 33%
• CO2 Insertion 33%
• Diiodides 33%
• Methyl Triflate 33%
• Silylated 33%

Chemistry

• Dinitrogen 100%
• Zirconocene 100%
• Carbon Dioxide 100%
• Hydrazine 100%
• Carboxylation 100%
• Zirconium 66%
• Nitrogen 66%
• Chemistry 33%
• Cyclopentadienyl 33%
• Regiochemistry 33%
• Stereochemistry 33%
• dimer 33%
• Triflate 33%