Bismuth, one of the heaviest semimetals in nature, ignited the interest of the materials physics community for its potential impact on topological quantummaterial systems that use its strong spin-orbit coupling and unique orbital hybridization. In particular, recent theoretical predictions of unique topological and superconducting properties of thin bismuth films and interfaces prompted intense research on the growth of submonolayers to a few monolayers of bismuth on different substrates. Similar to bulk rhombohedral bismuth, the initial growth of bismuth films on most substrates results in buckled bilayers that grow in either the (111) or (110) directions, with a lattice constant close to that of bulk Bi. By contrast, we show a new growth pattern for bismuth monolayers on NbSe2. We find that the initial growth of Bi can form a strongly bonded commensurate layer, resulting in a compressively strained twodimensional (2D) triangular lattice.We also observed unique pattern of 1D ripples and domain walls is observed. The single layer of bismuth also introduces strong marks on the electronic properties at the surface.
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