Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

Aaron M. Tondreau; Emil Lobkovsky; Paul J. Chirik

doi:10.1021/ol800906b

Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

Aaron M. Tondreau
, Emil Lobkovsky
, Paul J. Chirik

Research output: Contribution to journal › Article › peer-review

192 Scopus citations

Abstract

(Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH₃ or Ph₂SiH₂, representing one of the most active iron-catalyzed carbonyl reductions reported to date.

Original language	English (US)
Pages (from-to)	2789-2792
Number of pages	4
Journal	Organic letters
Volume	10
Issue number	13
DOIs	https://doi.org/10.1021/ol800906b
State	Published - 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation",

abstract = "(Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol \%) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl reductions reported to date.",

author = "Tondreau, \{Aaron M.\} and Emil Lobkovsky and Chirik, \{Paul J.\}",

year = "2008",

doi = "10.1021/ol800906b",

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journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

AU - Tondreau, Aaron M.

AU - Lobkovsky, Emil

AU - Chirik, Paul J.

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl reductions reported to date.

AB - (Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl reductions reported to date.

UR - https://www.scopus.com/pages/publications/59949090015

UR - https://www.scopus.com/pages/publications/59949090015#tab=citedBy

U2 - 10.1021/ol800906b

DO - 10.1021/ol800906b

M3 - Article

C2 - 18537247

AN - SCOPUS:59949090015

SN - 1523-7060

VL - 10

SP - 2789

EP - 2792

JO - Organic letters

JF - Organic letters

IS - 13

ER -

Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

Abstract

All Science Journal Classification (ASJC) codes

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