Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

Aaron M. Tondreau; Emil Lobkovsky; Paul J. Chirik

doi:10.1021/ol800906b

Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

Aaron M. Tondreau, Emil Lobkovsky, Paul J. Chirik

Research output: Contribution to journal › Article › peer-review

188 Scopus citations

Abstract

(Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH₃ or Ph₂SiH₂, representing one of the most active iron-catalyzed carbonyl reductions reported to date.

Original language	English (US)
Pages (from-to)	2789-2792
Number of pages	4
Journal	Organic letters
Volume	10
Issue number	13
DOIs	https://doi.org/10.1021/ol800906b
State	Published - 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol800906b

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title = "Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation",

abstract = "(Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl reductions reported to date.",

author = "Tondreau, {Aaron M.} and Emil Lobkovsky and Chirik, {Paul J.}",

year = "2008",

doi = "10.1021/ol800906b",

language = "English (US)",

volume = "10",

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journal = "Organic letters",

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T1 - Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

AU - Tondreau, Aaron M.

AU - Lobkovsky, Emil

AU - Chirik, Paul J.

PY - 2008

Y1 - 2008

N2 - (Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl reductions reported to date.

AB - (Chemical Equation Presented) Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective reduction of aldehydes and ketones. Efficient carbonyl hydrosilylation is observed at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl reductions reported to date.

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U2 - 10.1021/ol800906b

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JO - Organic letters

JF - Organic letters

IS - 13

ER -

Bis(imino)pyridine iron complexes for aldehyde and ketone hydrosilylation

Abstract

All Science Journal Classification (ASJC) codes

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