Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation

Keyphrases

• C-H Functionalization 100%
• C-H Activation 100%
• Hydroxylation 100%
• Ferryl 100%
• Rebound Mechanism 100%
• Functionalization Reaction 100%
• Radical Rebound 100%
• Radical Pairs 100%
• Oxygen Rebound 66%
• Biomimetic Catalyst 66%
• Small Molecules 33%
• Electron Transfer 33%
• Hydrogen Abstraction 33%
• Biotransformation 33%
• Recount 33%
• Olefins 33%
• Reaction Pathway 33%
• Energy Landscape 33%
• Oxygen Atom 33%
• Iron Oxide 33%
• Reduced Iron 33%
• Synthetic Organic Chemistry 33%
• Oxygenase 33%
• High-valent Iron-oxo Species 33%
• Desaturation 33%
• Iron-based Materials 33%
• Carbocations 33%
• New Chemistries 33%
• Cage Escape 33%
• Mechanistic Features 33%

Chemistry

• Dioxygen 100%
• Biomimetic Catalyst 100%
• hydroxylation 100%
• Hydrogen Atom 50%
• Alkene 50%
• Chemistry 50%
• Organic Chemistry 50%
• Oxygenase 50%
• Carbocation 50%
• Oxygen Atom 50%
• Electron Transfer 50%
• Energy Landscape 50%