Benzotrithiophene - A planar, electron-rich building block for organic semiconductors

Christian B. Nielsen; Jamie M. Fraser; Bob C. Schroeder; Junping Du; Andrew J.P. White; Weimin Zhang; Iain McCulloch

doi:10.1021/ol200643z

Benzotrithiophene - A planar, electron-rich building block for organic semiconductors

Christian B. Nielsen, Jamie M. Fraser, Bob C. Schroeder, Junping Du, Andrew J.P. White, Weimin Zhang, Iain McCulloch

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

Chemical equations presented. Several functionalized benzo[1,2-b:3,4- b′:5,6-d′′]trithiophenes have been synthesized and characterized. The fully planar and highly electron-rich material shows great promise as the donor constituent in donor-acceptor type copolymers for use in organic electronics. As a proof of concept, a copolymer with the electron acceptor, 2,1,3-benzothiadiazole, has been prepared. Side-chain modifications have been employed to adjust both the electron-rich character of the monomer and the solubility and processability of the polymer.

Original language	English (US)
Pages (from-to)	2414-2417
Number of pages	4
Journal	Organic letters
Volume	13
Issue number	9
DOIs	https://doi.org/10.1021/ol200643z
State	Published - May 6 2011
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol200643z

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title = "Benzotrithiophene - A planar, electron-rich building block for organic semiconductors",

abstract = "Chemical equations presented. Several functionalized benzo[1,2-b:3,4- b′:5,6-d′′]trithiophenes have been synthesized and characterized. The fully planar and highly electron-rich material shows great promise as the donor constituent in donor-acceptor type copolymers for use in organic electronics. As a proof of concept, a copolymer with the electron acceptor, 2,1,3-benzothiadiazole, has been prepared. Side-chain modifications have been employed to adjust both the electron-rich character of the monomer and the solubility and processability of the polymer.",

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month = may,

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doi = "10.1021/ol200643z",

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T1 - Benzotrithiophene - A planar, electron-rich building block for organic semiconductors

AU - Nielsen, Christian B.

AU - Fraser, Jamie M.

AU - Schroeder, Bob C.

AU - Du, Junping

AU - White, Andrew J.P.

AU - Zhang, Weimin

AU - McCulloch, Iain

PY - 2011/5/6

Y1 - 2011/5/6

N2 - Chemical equations presented. Several functionalized benzo[1,2-b:3,4- b′:5,6-d′′]trithiophenes have been synthesized and characterized. The fully planar and highly electron-rich material shows great promise as the donor constituent in donor-acceptor type copolymers for use in organic electronics. As a proof of concept, a copolymer with the electron acceptor, 2,1,3-benzothiadiazole, has been prepared. Side-chain modifications have been employed to adjust both the electron-rich character of the monomer and the solubility and processability of the polymer.

AB - Chemical equations presented. Several functionalized benzo[1,2-b:3,4- b′:5,6-d′′]trithiophenes have been synthesized and characterized. The fully planar and highly electron-rich material shows great promise as the donor constituent in donor-acceptor type copolymers for use in organic electronics. As a proof of concept, a copolymer with the electron acceptor, 2,1,3-benzothiadiazole, has been prepared. Side-chain modifications have been employed to adjust both the electron-rich character of the monomer and the solubility and processability of the polymer.

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JO - Organic letters

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Benzotrithiophene - A planar, electron-rich building block for organic semiconductors

Abstract

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