Asymmetric linker generates intrinsically disordered metal-organic framework with local MOF-74 structure

Bhavish Dinakar; Julius J. Oppenheim; Marco Vandone; Juan F. Torres; Andrei Iliescu; Zhentao Yang; Yuriy Román-Leshkov; Mircea Dincă

doi:10.1039/d5cc03713a

Asymmetric linker generates intrinsically disordered metal-organic framework with local MOF-74 structure

Bhavish Dinakar
, Julius J. Oppenheim
, Marco Vandone
, Juan F. Torres
, Andrei Iliescu
, Zhentao Yang
, Yuriy Román-Leshkov
, Mircea Dincă

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Here, we report an intrinsically disordered MOF in the MOF-74 family, Mg_2−x(as-dobpdc) (as-dobpdc⁴⁻ = 3′,4-dioxidobiphenyl-3,4′-dicarboxylate). Despite the absence of crystallinity, this material exhibits local ordering consistent with that of its crystalline isomers, maintains porosity, and exhibits a high density of open metal sites.

Original language	English (US)
Pages (from-to)	12590-12593
Number of pages	4
Journal	Chemical Communications
Volume	61
Issue number	67
DOIs	https://doi.org/10.1039/d5cc03713a
State	Published - Aug 14 2025
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d5cc03713a

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title = "Asymmetric linker generates intrinsically disordered metal-organic framework with local MOF-74 structure",

abstract = "Here, we report an intrinsically disordered MOF in the MOF-74 family, Mg2−x(as-dobpdc) (as-dobpdc4− = 3′,4-dioxidobiphenyl-3,4′-dicarboxylate). Despite the absence of crystallinity, this material exhibits local ordering consistent with that of its crystalline isomers, maintains porosity, and exhibits a high density of open metal sites.",

author = "Bhavish Dinakar and Oppenheim, \{Julius J.\} and Marco Vandone and Torres, \{Juan F.\} and Andrei Iliescu and Zhentao Yang and Yuriy Rom{\'a}n-Leshkov and Mircea Dinc{\u a}",

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month = aug,

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doi = "10.1039/d5cc03713a",

language = "English (US)",

volume = "61",

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journal = "Chemical Communications",

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TY - JOUR

T1 - Asymmetric linker generates intrinsically disordered metal-organic framework with local MOF-74 structure

AU - Dinakar, Bhavish

AU - Oppenheim, Julius J.

AU - Vandone, Marco

AU - Torres, Juan F.

AU - Iliescu, Andrei

AU - Yang, Zhentao

AU - Román-Leshkov, Yuriy

AU - Dincă, Mircea

PY - 2025/8/14

Y1 - 2025/8/14

N2 - Here, we report an intrinsically disordered MOF in the MOF-74 family, Mg2−x(as-dobpdc) (as-dobpdc4− = 3′,4-dioxidobiphenyl-3,4′-dicarboxylate). Despite the absence of crystallinity, this material exhibits local ordering consistent with that of its crystalline isomers, maintains porosity, and exhibits a high density of open metal sites.

AB - Here, we report an intrinsically disordered MOF in the MOF-74 family, Mg2−x(as-dobpdc) (as-dobpdc4− = 3′,4-dioxidobiphenyl-3,4′-dicarboxylate). Despite the absence of crystallinity, this material exhibits local ordering consistent with that of its crystalline isomers, maintains porosity, and exhibits a high density of open metal sites.

UR - https://www.scopus.com/pages/publications/105013107836

UR - https://www.scopus.com/pages/publications/105013107836#tab=citedBy

U2 - 10.1039/d5cc03713a

DO - 10.1039/d5cc03713a

M3 - Article

C2 - 40709519

AN - SCOPUS:105013107836

SN - 1359-7345

VL - 61

SP - 12590

EP - 12593

JO - Chemical Communications

JF - Chemical Communications

IS - 67

ER -

Asymmetric linker generates intrinsically disordered metal-organic framework with local MOF-74 structure

Abstract

All Science Journal Classification (ASJC) codes

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