Approaching disorder-free transport in high-mobility conjugated polymers

Deepak Venkateshvaran, Mark Nikolka, Aditya Sadhanala, Vincent Lemaur, Mateusz Zelazny, Michal Kepa, Michael Hurhangee, Auke Jisk Kronemeijer, Vincenzo Pecunia, Iyad Nasrallah, Igor Romanov, Katharina Broch, Iain McCulloch, David Emin, Yoann Olivier, Jerome Cornil, David Beljonne, Henning Sirringhaus

Research output: Contribution to journalArticlepeer-review

854 Scopus citations


Conjugated polymers enable the production of flexible semiconductor devices that can be processed from solution at low temperatures. Over the past 25 years, device performance has improved greatly as a wide variety of molecular structures have been studied. However, one major limitation has not been overcome; transport properties in polymer films are still limited by pervasive conformational and energetic disorder. This not only limits the rational design of materials with higher performance, but also prevents the study of physical phenomena associated with an extended I-electron delocalization along the polymer backbone. Here we report a comparative transport study of several high-mobility conjugated polymers by field-effect-modulated Seebeck, transistor and sub-bandgap optical absorption measurements. We show that in several of these polymers, most notably in a recently reported, indacenodithiophene-based donor-acceptor copolymer with a near-amorphous microstructure, the charge transport properties approach intrinsic disorder-free limits at which all molecular sites are thermally accessible. Molecular dynamics simulations identify the origin of this long sought-after regime as a planar, torsion-free backbone conformation that is surprisingly resilient to side-chain disorder. Our results provide molecular-design guidelines for disorder-free conjugated polymers.

Original languageEnglish (US)
Pages (from-to)384-388
Number of pages5
Issue number7527
StatePublished - Nov 20 2014
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General


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