Antiferromagnetism and metallic conductivity in Nb12O29

R. J. Cava, B. Batlogg, J. J. Krajewski, P. Gammel, H. F. Poulsen, W. F. Peck, L. W. Rupp

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Abstract

AT the heart of the controversy about the microscopic origin of superconductivity in high-transition-temperature copper oxide superconductors is the question of whether or not the antiferromagnetism associated with the single-hole Cu2+ 3d 9 state is of fundamental importance. To test whether this unconventional spin-mediated superconductivity might be electron/hole symmetric, oxides of the elements with single d-orbital electrons, such as Ti3+ (3d 1), Nb4+ (4d 1) and W5+ (5d 1), are of particular interest. Localized magnetic spin states and magnetic ordering have never been observed previously in transition-metal oxides with one or two electrons in the 4d or 5d states, because of the preference for conventional d-band metallic conductivity or for metal-metal bonding. In exploring the possibility of a d l-d 9 and ferroelec-tricity-superconductivity relationship in oxides (see, for instance, ref. 1), we have found that Nb12O29, a material with a 'crystallographic shear' structure, displays simultaneously both metallic conductivity, a signature of delocalized electrons, and local-moment magnetism with an antiferromagnetic ordering temperature of 12 K. This suggests that the bonding to oxygen of the 4d levels of early-transition-metal elements may not be sufficiently covalent to yield the kind of exotic conductivity (and thus exotic superconductivity) observed for copper oxides.

Original languageEnglish (US)
Pages (from-to)598-600
Number of pages3
JournalNature
Volume350
Issue number6319
DOIs
StatePublished - Jan 1 1991
Externally publishedYes

All Science Journal Classification (ASJC) codes

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    Cava, R. J., Batlogg, B., Krajewski, J. J., Gammel, P., Poulsen, H. F., Peck, W. F., & Rupp, L. W. (1991). Antiferromagnetism and metallic conductivity in Nb12O29. Nature, 350(6319), 598-600. https://doi.org/10.1038/350598a0