Antiferromagnetic Order in the Rare-Earth Halide Perovskites CsEuBr3and CsEuCl3

Daniel B. Straus, Tomasz Klimczuk, Xianghan Xu, Robert J. Cava

Research output: Contribution to journalArticlepeer-review

3 Scopus citations


Bulk CsEuBr3 and CsEuCl3 are experimentally shown to be magnetic semiconductors that order antiferromagnetically at Néel temperatures of 2.0 K and 1.0 K, respectively. Given that nanoparticles and thin films of CsEuCl3 have been reported to order ferromagnetically at a similar temperature, our observation of antiferromagnetic ordering in CsEuBr3 and CsEuCl3 expands the possible applications of halide perovskites to now include spintronic devices where both ferromagnetic and antiferromagnetic devices can be fabricated from a single material. The conclusion that CsEuCl3 can be used as a switchable magnetic material is also supported by our density-functional theory calculations.

Original languageEnglish (US)
Pages (from-to)10772-10777
Number of pages6
JournalChemistry of Materials
Issue number23
StatePublished - Dec 13 2022

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Chemical Engineering
  • Materials Chemistry


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